Synthesis and crystal and molecular structure of tetraphenyldibismuthine, Bi2Ph4, the first crystallographically characterized tetraorganyl derivative of bismuth(II)

Fausto Calderazzo (1) , Antonio Morvillo (2) , Giancarlo Pelizzi (3) , Rinaldo Poli (1)

1 University of Pisa - Università di Pisa
2 Unipd - Università degli Studi di Padova = University of Padua
3 UNIPR - Università degli studi di Parma = University of Parma

Tetraphenyldibismuthine, Bi2Ph4, was prepared by reducing BiPh2Cl with sodium in liquid ammonia and characterized by conventional methods, including X-ray diffractometry.

Domaines: Chimie de coordination

Fausto Calderazzo, Antonio Morvillo, Giancarlo Pelizzi, Rinaldo Poli. Synthesis and crystal and molecular structure of tetraphenyldibismuthine, Bi2Ph4, the first crystallographically characterized tetraorganyl derivative of bismuth(II). Journal of the Chemical Society, Chemical Communications, 1983, 9, pp.507-508. ⟨10.1039/C39830000507⟩. ⟨hal-03545517⟩