Synthesis of Mo2X4(PMe3)4 (Mo-4Mo) (X = Cl, Br, I) compounds by decarbonylation of Mo2X4(CO)8 and by comproportionation of Mo(CO)6 and MoX3(PMe3)3. X-ray crystal structure of Mo2I4(PMe3)4.2THF

F. Albert Cotton (1) , Rinaldo Poli (1)

1 Texas A&M University [College Station]

Domaines: Chimie de coordination; Cristallographie

F. Albert Cotton, Rinaldo Poli. Synthesis of Mo2X4(PMe3)4 (Mo-4Mo) (X = Cl, Br, I) compounds by decarbonylation of Mo2X4(CO)8 and by comproportionation of Mo(CO)6 and MoX3(PMe3)3. X-ray crystal structure of Mo2I4(PMe3)4.2THF. Inorganic Chemistry, 1987, 26 (19), pp.3228-3231. ⟨10.1021/ic00266a035⟩. ⟨hal-03545001⟩