Formation and structure of a quadruply-iodo-bridged complex of dimolybdenum( III , IV ), [(Cp*Mo) 2 (µ-l) 4 ]l 3 (Cp*=η 5 -C 5 Me 5 ) and its reversible oxidation and reduction

Rinaldo Poli (1) , John Gordon (1) , Jahanvi Desai (1) , Arnold Rheingold (2)

1 University of Maryland [College Park]
2 University of Delaware [Newark]

The mixed-valence quadruply-iodo-bridged [(Cp*Mo)2(µ-l)4]l3 has been crystallographically characterized; its cyclic voltammogram shows reversible oxidation and reduction processes and suggests that the [(Cp*Mo)2(µ-l)4]n+(n= 0,1,2) series of complexes is isostructural.

Domaines: Chimie de coordination; Cristallographie

Rinaldo Poli, John Gordon, Jahanvi Desai, Arnold Rheingold. Formation and structure of a quadruply-iodo-bridged complex of dimolybdenum( III , IV ), [(Cp*Mo) 2 (µ-l) 4 ]l 3 (Cp*=η 5 -C 5 Me 5 ) and its reversible oxidation and reduction. Journal of the Chemical Society, Chemical Communications, 1991, 21, pp.1518-1520. ⟨10.1039/C39910001518⟩. ⟨hal-03542767⟩