Upconversion-powered photoelectrochemistry.

Rony Khnayzer (1) , Jörg Blumhoff (1) , Jordan Harrington (1) , Alexandre Haefele (1) , Fan Deng (1) , Felix Castellano (1)

1 Center for Photochemical Sciences

Upconversion photochemistry occurring between palladium(II) octaethylporphyrin (PdOEP, 1) and 9,10-diphenylanthracene (DPA, 2) in toluene successfully sensitizes nanostructured WO(3) photoanodes (E(g) = 2.7 eV) to sub-bandgap non-coherent green photons at low power density.

Domaines: Chimie organique

Rony Khnayzer, Jörg Blumhoff, Jordan Harrington, Alexandre Haefele, Fan Deng, et al.. Upconversion-powered photoelectrochemistry.. Chemical Communications, 2012, 48 (2), pp.209-11. ⟨10.1039/c1cc16015j⟩. ⟨hal-02556088⟩