Artemisia Herba Alba Essential Oil as Green Corrosion Inhibitor for Aluminum in Hydrochloric Acid Solution

Nacer Hechiche (1) , Dalila Boughrara (1) , Abdelaziz Kadri (2, 1) , Nacera Dahmani , Nassima Benbrahim (3)

1 LPCM - Laboratoire de physique et de chimie des matériaux [Tizi-Ouzou]
2 UMMTO - Université Mouloud Mammeri [Tizi Ouzou]
3 Laboratoire de Matériaux, Electrochimie et Corrosion

Artemisia herba-alba essential oil extract was investigated as green inhibitor for aluminum corrosion in 1 M HCl solution. The chemical analysis obtained by gas chromatography and gas chromatography-mass spectrometry, revealed 68 components. The inhibition efficiency was determined by weight loss measurements, potentiodynamic polarization, electrochemical impedance spectroscopy and scanning electron microscope. The results revealed an increase of inhibition efficiency by maximum 92% trough increasing the oil concentration to 3 g/L at 333 K. The oil compounds adsorb by physisorption, follow Langmuir adsorption isotherm and act as mixed type inhibitors. The EIS results confirmed the adsorption mechanism process and the SEM observations.

Mots clés: Artemisia herba-alba; EIS; SEM; Acid inhibition; Aluminum

Domaines: Chimie; Chimie analytique; Matériaux

Nacer Hechiche, Dalila Boughrara, Abdelaziz Kadri, Nacera Dahmani, Nassima Benbrahim. Artemisia Herba Alba Essential Oil as Green Corrosion Inhibitor for Aluminum in Hydrochloric Acid Solution. Analytical and Bioanalytical Electrochemistry, 2019, 11, pp.1129 - 1147. ⟨hal-02428588⟩