Fluorescence Detection of Surface-Bound Intermediates Produced from UV Photoreactivity of Alkylsiloxane SAMs

Abstract : Detection and quantification of submonolayer coverage surface species is not trivial. We have developed a novel method sensitive to surface-bound chemical functional groups as low as 10(11) molecules/cm(2) by specific covalent attachment of fluorescent chromophores. This enables the intermediates of the UV photochemistry of alkylsiloxane self-assembled monolayers to be identified.
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https://hal.archives-ouvertes.fr/hal-02090743
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Submitted on : Friday, April 5, 2019 - 10:08:10 AM
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Eric Mcarthur, Tao Ye, Jason Cross, Stephane Petoud, Eric Borguet. Fluorescence Detection of Surface-Bound Intermediates Produced from UV Photoreactivity of Alkylsiloxane SAMs. Journal of the American Chemical Society, American Chemical Society, 2004, 126 (8), pp.2260-2261. ⟨10.1021/ja038062n⟩. ⟨hal-02090743⟩

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