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Synthesis of new cellulose ethers using Suzuki–Miyaura reactions

Abstract : Cellulose ethers are functionalized biopolymers that are industrially produced through drastic conditions employing gaseous reactants with a high risk of industrial accident. The cellulose ethers that are commercially available generally bear short carbon-chains. In this work, an alternative method using non-gaseous chemicals is proposed. It relies on the use of the Suzuki–Miyaura reaction employing mild, moisture- and air-stable conditions. Relatively innocuous reagents are used for this step, which allows the formation of a wide range of cellulose ethers bearing various functional groups with different chain-length.
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https://hal.archives-ouvertes.fr/hal-02064857
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Submitted on : Tuesday, March 12, 2019 - 11:31:49 AM
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Cédric Goncalves, Camille Favre, Pierre Feuardant, Sarah Klein, Carlos Vaca-Garcia, et al.. Synthesis of new cellulose ethers using Suzuki–Miyaura reactions. Carbohydrate Polymers, Elsevier, 2015, 116, pp.51-59. ⟨10.1016/j.carbpol.2014.03.089⟩. ⟨hal-02064857⟩

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