Activation of the C−H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy) 2+ /2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System

Carine Michel , Paola Belanzoni (1) , Patrick Gamez (2) , Jan Reedijk (2) , Evert Jan Baerends (1)

1 Department of Chemistry, University of Perugia
2 Leiden Institute of Chemistry

Domaines: Chimie; Catalyse

Carine Michel, Paola Belanzoni, Patrick Gamez, Jan Reedijk, Evert Jan Baerends. Activation of the C−H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy) 2+ /2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System. Inorganic Chemistry, 2009, 48 (24), pp.11909 - 11920. ⟨10.1021/ic902155m⟩. ⟨hal-01899081⟩