First Isolation and Structural Characterization of N-base Adducts of Mono- and Perfluoroaryliodine(III) Compounds, ArfIX2 (X = F, CN)

Hermann-Josef Frohn (1) , Markus E. Hirschberg (1) , Ulrich Westphal (1) , Roland Boese (1) , Ulrich Floerke (2) , Dieter Bläser (1)

1 Inorganic Chemistry
2 Inorganic and Analytical Chemistry

The adducts of aryliodinedifluorides ArfIF2, (Arf = C6F5; x-FC6H4, x = 2, 3, 4) and aryliodinedicyanide 4-FC6H4I(CN)2 with N-bases (phenanthroline, 2,2'-bipyridine, and quinoline) were isolated and characterized by their single crystal structure, Raman spectra, and their multi nuclear magnetic resonance spectra in solution. Their properties and their thermal decomposition are discussed with respect to the non-coordinated analogues.

Mots clés: Physical Sciences

Hermann-Josef Frohn, Markus E. Hirschberg, Ulrich Westphal, Roland Boese, Ulrich Floerke, et al.. First Isolation and Structural Characterization of N-base Adducts of Mono- and Perfluoroaryliodine(III) Compounds, ArfIX2 (X = F, CN). Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2009, 635 (13-14), pp.2249. ⟨10.1002/zaac.200900169⟩. ⟨hal-00484138⟩