Experimental determination of intragranular helium diffusion rates in boron carbide (B4C)

Denis Horlait (1) , Dominique Gosset (2) , Aurélien Jankowiak (2) , Vianney Motte (2) , Nicolas Lochet (2) , Thierry Sauvage (3) , Eric Gilabert (4)

1 ICSM - UMR 5257 - Institut de Chimie Séparative de Marcoule
2 SRMA - Service des Recherches Métallurgiques Appliquées
3 CEMHTI - Conditions Extrêmes et Matériaux : Haute Température et Irradiation
4 CNAB - Chimie Nucléaire Analytique et Bio-environnementale

Boron carbide, B 4 C, is widely used as a neutron absorber in nuclear reactors. Since neutron absorption by 10 B leads to 4 He production, it appears necessary to study He behavior and its possible effects on the B 4 C ceramic. In this study, the diffusion characteristics of ion-implanted He in B 4 C (500 keV, fluences from 1 x 10 +13 to 2 x 10 +15 He.cm-2) were investigated mainly by Thermo-Desorption Spectroscopy (TDS) from 600°C up to B 4 C melting point. The experiments were done on dense B 4 C samples having large grains (30-60 µm) to render grain boundaries effects on He outward diffusion ineffective and thus to access intragranular He diffusion kinetics. From controlled temperature ramp experiments, it was notably observed that He release was realized in two main stages. A first He population was able to exit the material at moderate temperatures by interstitial diffusion. Then a second population was quantitatively released only over 1150°C. This was attributed to He atoms that, in their initial interstitial diffusion course at moderate temperatures from their implantation sites, got trapped in defect aggregates and/or He bubbles. As the nucleations of both these traps are expected to be related to helium and irradiation defect concentrations, the ratio of the two He populations was indeed found to be correlated with the implantation fluence. From the obtained He release curves, the apparent activation energies (E a) of He intragranular diffusion in B 4 C was determined (2.6-3.1 eV) in the 800-1100°C temperature range. This value appears slightly higher than the one determined at lower temperatures, hinting that a change in diffusion mechanism may occur around 800°C. The apparent E a of He detrapping from He bubbles (~2.5 eV) and from defect aggregates (~4 eV) were also determined for temperatures within 1200-1500°C.

Domaines: Chimie analytique; Matériaux; Radiochimie; Chimie-Physique [physics.chem-ph]

Denis Horlait, Dominique Gosset, Aurélien Jankowiak, Vianney Motte, Nicolas Lochet, et al.. Experimental determination of intragranular helium diffusion rates in boron carbide (B4C). Journal of Nuclear Materials, 2019, 527, pp.151834. ⟨10.1016/j.jnucmat.2019.151834⟩. ⟨hal-02346779⟩