Effects on CHP plant efficiency of H 2 production through partial oxydation of natural gas over two group VIII metal catalysts

Olivier Le Corre (1, 2) , Khalil Saikaly (3) , Marc A. Rosen (4)

1 GEPEA - Laboratoire de génie des procédés - environnement - agroalimentaire
2 Mines Nantes - Mines Nantes
3 Water Research Center
4 Faculty of Engineering and Applied Science

Blending H 2 with natural gas in spark ignition engines can increase for electric efficiency. In-situ H 2 production for spark ignition engines fuelled by natural gas has therefore been investigated recently, and reformed exhaust gas recirculation (RGR) has been identified a potentially advantageous approach: RGR uses the steam and O 2 contained in exhaust gases under lean combustion, for reforming natural gas and producing H 2, CO, and CO 2. In this paper, an alternative approach is introduced: air gas reforming circulation (AGRC). AGRC uses directly the O 2 contained in air, rendering the chemical pathway comparable to partial oxidation. Formulations based on palladium and platinum have been selected as potential catalysts. With AGRC, the concentrations of the constituents of the reformed gas are approximately 25% hydrogen, 10% carbon monoxide, 8% unconverted hydrocarbons and 55% nitrogen. Experimental results are presented for the electric efficiency and exhaust gas (CO and HC) composition of the overall system (SI engine equipped with AGRC). It is demonstrated that the electric efficiency can increase for specific ratios of air to natural gas over the catalyst. Although the electric efficiency gain with AGRC is modest at around 0.2%, AGRC can be cost effective because of its straightforward and inexpensive implementation. Misfiring and knock were both not observed in the tests reported here. Nevertheless, technical means of avoiding knock are described by adjusting the main flow of natural gas and the additional flow of AGRC. Copyright © 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Mots clés: Alternative approach; Chemical pathways; CHP; CHP plant; Cost effective; Electric efficiency; Group VIII metals; In-situ; Lean combustion; Oxydation; Partial oxidations; Power; SI Engines; Blending; Carbon dioxide; Carbon monoxide; Catalysts; Efficiency; Exhaust gases; Hydrocarbons; Hydrogen; In situ combustion; Nitrogen; Palladium; Platinum; Steam reforming; Natural gas

Domaines: Sciences de l'ingénieur [physics]

Olivier Le Corre, Khalil Saikaly, Marc A. Rosen. Effects on CHP plant efficiency of H 2 production through partial oxydation of natural gas over two group VIII metal catalysts. International Journal of Hydrogen Energy, 2012, 37 (13), pp.10380-10389. ⟨10.1016/j.ijhydene.2012.04.015⟩. ⟨hal-00841027⟩