Vegetable ash as raw material in the production of glasses and enamels, for example the contemporary vegetable ashes from Burgundy, France

Philippe Colomban (1) , Aurélie Tournié (1) , Frère Daniel de Montmollin (1) , Frère Luc Krainhoefner (1)

1 LADIR - Laboratoire de Dynamique Interactions et Réactivité

The powdery nature and high alkali content of vegetable ashes make them ideal raw materials to be used as modifiers of silicate compositions (glasses, enamels and ceramics). Their utilisation since ancient times is described in the literature of the history of glasses, but studies on the analyses of their composition are still limited. We discuss here the compositions of tree and shrub ashes (wattle, hawthorn, oak, green oak, olive wood, elm, poplar, apple tree, vine shoot), of plants (carex, fern, dogwood), of cereals (wheat, maize, rice), threshing waste and hay, mainly harvested in Maconnais, near Taizé (Saône-et-Loire, France), by the potter Brother D. de Montmolin. The contributions in alkali modifiers (Na2O, K2O), alkaline-earth (CaO, MgO) and in silica are discussed in view of the data gathered from the literature of the history of techniques used in the production of ceramics, enamels and glasses. The huge variation in composition is usually attributed to recycling and is questioned by the very broad range of compositions that we obtained in the analyses of the ashes.

Mots clés: ashes; wood; plants; cereals; composition; glass; pottery; glaze; Raman

Domaines: Science des matériaux [cond-mat.mtrl-sci]

Philippe Colomban, Aurélie Tournié, Frère Daniel de Montmollin, Frère Luc Krainhoefner. Vegetable ash as raw material in the production of glasses and enamels, for example the contemporary vegetable ashes from Burgundy, France. 2010. ⟨hal-00542830⟩