Aging dynamics in Laponite dispersions at various salt concentrations
Résumé
The aging dynamics of a charged colloidal system, Laponite suspensions in water, has been investigated by photon correlation technique. The samples have been studied in a novel and very wide range of clay concentrations (Cw=0.3÷3.1 % in weight) and at four different NaCl salt concentrations (Cs=1x10-4 M; 1x10-3 M; 2x10-3 M; 5x10-3 M) aiming to investigate the widely discussed phase diagram which has been subject of discussion in the recent literature. A clear image of Laponite phase diagram has been obtained. The measurements show the existence of two different dynamical routes to reach a final arrested state and the presence of a transition line between them in the Cw-Cs plane.
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