[t-BuC(Ni-Pr)2]2Zn as Starting Reagent for Monoamidinate Zinc Complexes [t-BuC(Ni-Pr)2]ZnX

Sarah Schmidt (1) , Stephan Schulz (1) , Michael Bolte (2)

1 Institut für Anorganische Chemie
2 Institut für Anorganische Chemie [Frankfurt am Main]

Reaction of the bisamidinate zinc complex [t-BuC(Ni-Pr)2]2Zn 1 with ZnMe2 yielded the corresponding monoamidinate zinc complex {[t-BuC(Ni-Pr)2]ZnMe}2 2. 2 reacts with iodine with formation of {[t-BuC(Ni-Pr)2]ZnI}2 3). 2 and 3 both adopt dimeric structures in the solid state as was shown by single crystal X-ray analyses. 2 and 3 were characterized by elemental analyses, mass and multinuclear (1H, 13C{1H}) NMR spectroscopy (1H, 13C). In addition, X-ray crystal structures of 1 – 3 are reported.

Mots clés: Physical Sciences

Sarah Schmidt, Stephan Schulz, Michael Bolte. [t-BuC(Ni-Pr)2]2Zn as Starting Reagent for Monoamidinate Zinc Complexes [t-BuC(Ni-Pr)2]ZnX. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2009, 635 (13-14), pp.2210. ⟨10.1002/zaac.200900227⟩. ⟨hal-00495063⟩