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| HAL : hal-00366191, version 1 |
| Fiche détaillée |  Récupérer au format |
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| Journal of Molecular Catalysis B: Enzymatic 57 (2009) 6-9 |
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| Preparative scale enzymatic synthesis of D-sedoheptulose-7-phosphate from β-hydroxypyruvate and D-ribose-5-phosphate |
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| Franck Charmantray 1Virgil Hélaine 1 |
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| (2009) |
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| An enzymatic method for ready access to D-sedoheptulose-7-phosphate on a preparative scale was developed, based on the irreversible transketolase-catalyzed reaction: β-hydroxypyruvate + D-ribose-5- phosphate → D-sedoheptulose-7-phosphate. D-Sedoheptulose-7-phosphate disodium salt was obtained in 81% overall yield determined using a standard curve obtained by LC/MS/MS. |
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| 1 : | Synthèse et étude de systèmes à intêret biologique (SEESIB) |
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CNRS : UMR6504 – Université Blaise Pascal - Clermont-Ferrand II |
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| Domaine | : | Chimie/Catalyse |
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| D-Sedoheptulose-7-phosphate – Biocatalysis – Transketolase |
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| Liste des fichiers attachés à ce document : | |||||
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| hal-00366191, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00366191 | |
| oai:hal.archives-ouvertes.fr:hal-00366191 | |
| Contributeur : Stéphanie Bonnefoy | |
| Soumis le : Vendredi 6 Mars 2009, 10:17:10 | |
| Dernière modification le : Vendredi 6 Mars 2009, 10:28:07 | |
