Ice nucleation of ammonia gas exposed montmorillonite mineral dust particles

A. Salam (1, 2) , U. Lohmann (1, 3) , G. Lesins (1)

1 Department of Physics and Atmospheric Science [Halifax]
2 Department of Chemistry
3 IAC - Institute for Atmospheric and Climate Science [Zürich]

The ice nucleation characteristics of montmorillonite mineral dust aerosols with and without exposure to ammonia gas were measured at different atmospheric temperatures and relative humidities with a continuous flow diffusion chamber. The montmorillonite particles were exposed to pure (100%) and diluted ammonia gas (25 ppm) at room temperature in a stainless steel chamber. There was no significant change in the mineral dust particle size distribution due to the ammonia gas exposure. 100% pure ammonia gas exposure enhanced the ice nucleating fraction of montmorillonite mineral dust particles 3 to 8 times at 90% relative humidity with respect to water (RHw) and 5 to 8 times at 100% RHw for 120 min exposure time within our experimental conditions. The percentages of active ice nuclei were 2 to 9 times higher at 90% RHw and 2 to 13 times higher at 100% RHw in 25 ppm ammonia exposed montmorillonite compared to unexposed montmorillonite. All montmorillonite particles are more efficient as ice nuclei with increasing relative humidities and decreasing temperatures. The activation temperature of montmorillonite exposed to 100% pure ammonia was 12°C higher than for unexposed montmorillonite particles at 90% RHw and 10°C higher at 100% RHw. In the 25 ppm ammonia exposed montmorillonite experiments, the activation temperature was 7°C warmer than unexposed montmorillonite at 100% RHw. Degassing does not reverse the ice nucleating ability of ammonia exposed montmorillonite mineral dust particles. This is the first experimental evidence that ammonia gas exposed montmorillonite mineral dust particles can enhance its activation as ice nuclei and that the activation can occur at temperatures warmer than ?10°C where natural atmospheric ice nuclei are very scarce.

Domaines: Océan, Atmosphère

A. Salam, U. Lohmann, G. Lesins. Ice nucleation of ammonia gas exposed montmorillonite mineral dust particles. Atmospheric Chemistry and Physics Discussions, 2007, 7 (1), pp.383-403. ⟨hal-00302404⟩