Synthesis, Structural Characterization of the first N-heterocyclic carbene ligand fused to a porphyrin

Sébastien Richeter (1) , Aurélie Hadj-Aïssa (1) , Céline Taffin (1) , Arie van Der Lee (2) , Dominique Leclercq (1)

1 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
2 IEM - Institut Européen des membranes

The fonctionalization of two neighboring b-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene, the subsequent metallation of this external coordination site by palladium(II) and the structural characterization of the compounds obtained are presented.

Domaines: Chimie de coordination

Sébastien Richeter, Aurélie Hadj-Aïssa, Céline Taffin, Arie van Der Lee, Dominique Leclercq. Synthesis, Structural Characterization of the first N-heterocyclic carbene ligand fused to a porphyrin. Chemical Communications, 2007, pp.2148-2150. ⟨10.1039/b704681b⟩. ⟨hal-00183367⟩