Compound-specific isotope analysis. Application to archaelogy, biomedical sciences, biosynthesis, environment, extraterrestrial chemistry, food science, forensic science, humic substances, microbiology, organic geochemistry, soil science and sport.
Résumé
The isotopic composition, for example, 14C/12C, 13C/12C, 2H/1H, 15N/14N and 18O/16O, of the elements of matter is heterogeneous. It is ruled by physical, chemical and biological mechanisms. Isotopes can be employed to follow the fate of mineral and organic compounds during biogeochemical transformations. The determination of the isotopic composition of organic substances occurring at trace level in very complex mixtures such as sediments, soils and blood, has been made possible during the last 20 years due to the rapid development of molecular level isotopic techniques. After a brief glance at pioneering studies revealing isotopic breakthroughs at the molecular and intramolecular levels, this paper reviews selected applications of compound-specific isotope analysis in various scientific fields.
Mots clés
soil science
collagen
glucose
food science
plasma
organic geochemistry
protein
archaeology
amino acid
CSIA
triglycerides
18O
sediments
15N
petroleum
2H
CH4
14C
greenhouse gas
13C
meteorite
GC-IRMS
glycoside
IRMS
flavour
CO2
ethanol
review
morphine
sport
lignin
PAHs
PLFA
fatty acids
archae
n-alkanes
alkenone
forensic science
n-alcohol
humic substances
testosterone
lipids
alga
cholesterol
blood
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