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| HAL : hal-00142434, version 1 |
| arXiv : 0704.2480 |
| Fiche détaillée |  Récupérer au format |
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| jounal of material chemistry 16 (2006) 3489 |
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| MAGNETIC COUPLING AND LONG-RANGE ORDER IN THE SPIN-CHAIN SULPHIDE Ba2CoS3 |
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| Andrew D. J. Barnes 1Thomas Baikie 2 |
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| (28/07/2006) |
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| In this paper, we report on the magnetic properties of Ba2CoS3, a spin-chain compound recently found to be the first Co2+ containing one-dimensional sulphide to show metallic-like conductivity and negative magnetoresistance. We carried out an in-depth experimental investigation of the local structure of the cobalt atoms, and ab-initio calculations of the resulting electronic configuration of Co2+. From theoretical considerations, the intra-chain coupling was predicted to be antiferromagnetic. Experimentally, several estimates of this magnetic coupling were derived by analysing the temperature dependence of the magnetic susceptibility. Magnetic and heat capacity measurements also provided evidence of a three-dimensional antiferromagnetic ordering, a feature indicative of a noticeable inter-chain coupling in this quasi-1D system. |
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| 1 : | Department of Chemistry |
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University of Hull |
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| 2 : | Division of Materials Science |
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Nanyang Technological University |
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| 3 : | Laboratoire de cristallographie et sciences des matériaux (CRISMAT) |
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CNRS : UMR6508 – Université de Caen – Ecole Nationale Supérieure d'Ingénieurs de Caen |
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| Domaine | : | Physique/Matière Condensée/Electrons fortement corrélés |
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| Liste des fichiers attachés à ce document : | |||||
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| hal-00142434, version 1 | |
| http://hal.archives-ouvertes.fr/hal-00142434 | |
| oai:hal.archives-ouvertes.fr:hal-00142434 | |
| Contributeur : Marie-Bernadette Lepetit | |
| Soumis le : Jeudi 19 Avril 2007, 10:31:22 | |
| Dernière modification le : Jeudi 19 Avril 2007, 10:45:44 | |
