V. Jonas and G. Frenking, Studies on the boron?nitrogen bond length of the classical donor?acceptor complex H3N?BF3, J. Chem. Soc., Chem. Commun., issue.12, pp.1489-1490, 1994.

W. T. Klooster, T. F. Koetzle, P. E. Siegbahn, T. B. Richardson, and R. H. Crabtree, Study of the N?H···H?B Dihydrogen Bond Including the Crystal Structure of BH3NH3by Neutron Diffraction, Journal of the American Chemical Society, vol.121, issue.27, pp.6337-6343, 1999.

D. Bonifazi, F. Fasano, M. M. Lorenzo-garcia, D. Marinelli, H. Oubaha et al., Boron?nitrogen doped carbon scaffolding: organic chemistry, self-assembly and materials applications of borazine and its derivatives, Chemical Communications, vol.51, issue.83, pp.15222-15236, 2015.

A. Staubitz, A. P. Robertson, M. E. Sloan, and I. Manners, Amine? and Phosphine?Borane Adducts: New Interest in Old Molecules, Chemical Reviews, vol.110, issue.7, pp.4023-4078, 2010.

K. Niedenzu and J. W. Dawson, Boron-Nitrogen Compounds. II.1,2Aminoboranes, Part 1: The Preparation of Organic Substituted Aminoboranes through a Grignard Reaction, Journal of the American Chemical Society, vol.81, issue.21, pp.5553-5555, 1959.

C. E. Wiberg, Das ?anorganische Benzol? B3N3H6 und seine Methylhomologen, Die Naturwissenschaften, vol.35, issue.7, pp.212-218, 1948.

J. Goubeau and H. J. Becher, Die Schwingungsspektren des Bortrimethyls und des Bortrimethyl-Ammoniakats, Zeitschrift f?r anorganische und allgemeine Chemie, vol.268, issue.1-2, pp.1-12, 1952.

I. , Tendance à l'oligomérisation

, PARTIR DE CE QUI EST POSITIF, CE QUI EST À AMÉLIORER, CE QUI FONCTIONNE BIEN?, Des stratégies réflexives-interactives pour le développement de compétences, pp.143-146, 2012.

L. Brunet, L?adoption au sein des couples de même sexe : une « falsification » de la réalité ?, Mariage de même sexe et filiation, pp.89-101, 2013.

H. J. Becher, ?ber den Bindungszustand in Bor?Stickstoff-Verbindungen. II. Bindungsmomente in Borazanen und Borazenen, Zeitschrift f?r anorganische und allgemeine Chemie, vol.270, issue.5-6, pp.273-286, 1952.

R. Hoffmann, Theoretical Investigations on Boron-Nitrogen Molecules, Advances in Chemistry, vol.42, pp.78-86, 1964.

W. S. Brey, M. E. Fuller, G. E. Ryschkewitsch, and A. S. Marshall, Proton Magnetic Resonance Study of Bonding in Aminoboranes and Substituted Pyridine-Boranes, Advances in Chemistry, vol.42, pp.100-107, 1964.

S. Trudel and D. F. Gilson, High-Pressure Raman Spectroscopic Study of the Ammonia?Borane Complex. Evidence for the Dihydrogen Bond, Inorganic Chemistry, vol.42, issue.8, pp.2814-2816, 2003.

C. Brown, R. H. Cragg, T. J. Miller, and D. O. Smith, Organoboron compounds, Journal of Organometallic Chemistry, vol.244, issue.3, pp.209-215, 1983.

H. Watanabe, K. Nagasawa, T. Totani, T. Yoshizaki, T. Nakagawa et al., Proton Magnetic Resonance of Aminoborane Derivatives, Advances in Chemistry, pp.108-115, 1964.

J. Goubeau, The Force Constants of Various Boron-Nitrogen Compounds, Advances in Chemistry, pp.87-94, 1964.

C. A. Jaska, K. Temple, A. J. Lough, and I. Manners, Transition Metal-Catalyzed Formation of Boron?Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines, Journal of the American Chemical Society, vol.125, issue.31, pp.9424-9434, 2003.

K. W. Böddeker, S. G. Shore, and R. K. Bunting, Boron-Nitrogen Chemistry. I. Syntheses and Properties of New Cycloborazanes, (BH2NH2)n1,2, Journal of the American Chemical Society, vol.88, issue.19, pp.4396-4401, 1966.

O. C. Musgrave, 829. The preparation of some dimeric sec.-Aminoboron dihalides, Journal of the Chemical Society (Resumed), p.4305, 1956.

, Rappels bibliographiques, Labyrinthe, issue.6, p.110, 2000.

O. J. Metters, A. M. Chapman, A. P. Robertson, C. H. Woodall, P. J. Gates et al., Generation of aminoborane monomers RR?N?BH2from amine?boronium cations [RR?NH?BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperature, Chem. Commun., vol.50, issue.81, pp.12146-12149, 2014.

D. A. Resendiz-lara, N. E. Stubbs, M. I. Arz, N. E. Pridmore, H. A. Sparkes et al., Boron?nitrogen main chain analogues of polystyrene: poly(B-aryl)aminoboranes via catalytic dehydrocoupling, Chem. Commun., vol.53, issue.85, pp.11701-11704, 2017.

G. M. Adams, A. L. Colebatch, J. T. Skornia, A. I. Mckay, H. C. Johnson et al., Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts, Journal of the American Chemical Society, vol.140, issue.4, pp.1481-1495, 2018.

B. Carboni and L. Monnier, Recent developments in the chemistry of amine- and phosphine-boranes, Tetrahedron, vol.55, issue.5, pp.1197-1248, 1999.

E. J. Corey and C. J. , Spotlights on our sister journals: Angew. Chem. Int. Ed. 37/2012, Angewandte Chemie International Edition, vol.51, issue.37, pp.9206-9209, 2012.

A. Cruz, E. Gen??z, and R. Contreras, 1,3-Heterazolidin-2-one as starting materials for optically active 1,3,2-oxazaborolines and 1,3,2-diazaboroline derived from ephedrines, Tetrahedron: Asymmetry, vol.9, issue.22, pp.3991-3996, 1998.

J. S. Merriam, K. Niedenzu, and N. E. Miller, 1,3-Diaza-2-Boracycloalkanes, Inorganic Syntheses, pp.164-167, 2007.

E. J. Corey, R. Imwinkelried, S. Pikul, and Y. B. Xiang, Practical enantioselective Diels-Alder and aldol reactions using a new chiral controller system, Journal of the American Chemical Society, vol.111, issue.14, pp.5493-5495, 1989.

S. Sato, H. Watanabe, and M. Asami, Catalytic asymmetric borane reduction of prochiral ketones by the use of diazaborolidine catalysts prepared from chiral ?-diamines, Tetrahedron: Asymmetry, vol.11, issue.21, pp.4329-4340, 2000.

, Rappels bibliographiques, Labyrinthe, issue.6, p.110, 2000.

M. Gazvoda, K. Höferl-prantz, R. Barth, W. Felzmann, A. Pevec et al., Completely Stereocontrolled Aldol Reaction of Chiral ?-Amino Acids, Organic Letters, vol.17, issue.3, pp.512-515, 2015.

W. Gerrard, M. F. Lappert, and C. A. Pearce, 69. Alkyl bisdialkylaminoboronites and related compounds, Journal of the Chemical Society (Resumed), p.381, 1957.

J. Haberecht, A. Krummland, F. Breher, B. Gebhardt, H. Rüegger et al., Functionalized borazines as precursors for new silica gels, Dalton Trans., issue.11, pp.2126-2132, 2003.

R. J. Brotherton, H. Steinberg, and O. Chem, , vol.2, p.80, 1966.

J. F. Brown, Dimethylaminoboron Dichloride and Difluoride, Journal of the American Chemical Society, vol.74, issue.5, pp.1219-1221, 1952.

P. Y. Chavant and M. Vaultier, Preparation of some organo-bis(diisopropylamino)boranes and their application to the synthesis of oxazaborolidines, Journal of Organometallic Chemistry, vol.455, issue.1-2, pp.37-46, 1993.

H. Nöth and P. Fritz, Zeitschrift für Anorg. und Allg. Chemie, vol.322, pp.297-309, 1963.

, Rappels bibliographiques, Labyrinthe, issue.6, p.110, 2000.

, L'aide fournie aux ménages modestes est limitée au Japon, 2014.

, Iridium-Catalyzed Selective Hydroboration of Substituted Allylic Amides, Schéma, vol.26

, Très peu d'individus ont accès aux prêts hypothécaires en Côte d'Ivoire, La réaction générale fonctionne aussi bien avec les alcynes riches en électrons (R1 = Me, 2016.

M. Bergère, Chapitre V. L?épuration des fonctions publiques, Une société en épuration, pp.181-231

, Divers organismes peuvent être impliqués dans les transitions (2016), 2018.

J. Frederick, J. Cavallo, and R. Wagner, J. Org. Chem, vol.26, pp.2157-2158, 1961.

N. Iwadate and M. Suginome, Synthesis of masked haloareneboronic acids via iridium-catalyzed aromatic C?H borylation with 1,8-naphthalenediaminatoborane (danBH), Journal of Organometallic Chemistry, vol.694, issue.11, pp.1713-1717, 2009.

H. C. Brown, P. Heim, and N. M. Yoon, Selective reductions. XV. Reaction of diborane in tetrahydrofuran with selected organic compounds containing representative functional groups, Journal of the American Chemical Society, vol.92, issue.6, pp.1637-1646, 1970.

, Rappels bibliographiques, Labyrinthe, issue.6, p.110, 2000.

A. W. Van-den, C. O. Berg, and . Areán, Chem. Commun, pp.668-681, 2008.

H. Kajiura, S. Tsutsui, K. Kadono, M. Kakuta, M. Ata et al., Hydrogen storage capacity of commercially available carbon materials at room temperature, Applied Physics Letters, vol.82, issue.7, pp.1105-1107, 2003.

J. Dong, X. Wang, H. Xu, Q. Zhao, and J. Li, Hydrogen storage in several microporous zeolites, International Journal of Hydrogen Energy, vol.32, issue.18, pp.4998-5004, 2007.

Z. Yang, Y. Xia, and R. Mokaya, Enhanced Hydrogen Storage Capacity of High Surface Area Zeolite-like Carbon Materials, Journal of the American Chemical Society, vol.129, issue.6, pp.1673-1679, 2007.

Y. Li and R. T. Yang, Significantly Enhanced Hydrogen Storage in Metal?Organic Frameworks via Spillover, Journal of the American Chemical Society, vol.128, issue.3, pp.726-727, 2006.

J. Yang, A. Sudik, D. J. Siegel, D. Halliday, A. Drews et al., A Self-Catalyzing Hydrogen-Storage Material, Angewandte Chemie International Edition, vol.47, issue.5, pp.882-887, 2008.

T. B. Marder, Will We Soon Be Fueling our Automobiles with Ammonia?Borane?, Angewandte Chemie International Edition, vol.46, issue.43, pp.8116-8118, 2007.

H. Jiang and Q. Xu, Erratum to ?Catalytic hydrolysis of ammonia borane for chemical hydrogen storage? [Catal. Today 170 (2011) 56?63], Catalysis Today, vol.182, issue.1, p.82, 2012.

C. W. Yoon, P. J. Carroll, and L. G. Sneddon, Ammonia Triborane: A New Synthesis, Structural Determinations, and Hydrolytic Hydrogen-Release Properties, Journal of the American Chemical Society, vol.131, issue.2, pp.855-864, 2009.

H. Jiang, T. Akita, and Q. Xu, A one-pot protocol for synthesis of non-noble metal-based core?shell nanoparticles under ambient conditions: toward highly active and cost-effective catalysts for hydrolytic dehydrogenation of NH3BH3, Chemical Communications, vol.47, issue.39, p.10999, 2011.

Q. Yao, Z. Lu, Y. Hu, and X. Chen, Core?shell Co@SiO2 nanosphere immobilized Ag nanoparticles for hydrogen evolution from ammonia borane, RSC Advances, vol.6, issue.92, pp.89450-89456, 2016.

F. P. Kinik, T. N. Nguyen, E. Oveisi, B. Valizadeh, F. M. Ebrahim et al., Discovery of a self-healing catalyst for the hydrolytic dehydrogenation of ammonia borane, Journal of Materials Chemistry A, vol.7, issue.41, pp.23830-23837, 2019.

Y. Zhao, Y. Kim, A. C. Dillon, M. J. Heben, and S. B. Zhang, Hydrogen Storage in Novel Organometallic Buckyballs, Physical Review Letters, vol.94, issue.15, p.155504, 2005.

R. Nirmala, H. Y. Kim, C. Yi, N. A. Barakat, R. Navamathavan et al., Electrospun nickel doped titanium dioxide nanofibers as an effective photocatalyst for the hydrolytic dehydrogenation of ammonia borane, International Journal of Hydrogen Energy, vol.37, issue.13, pp.10036-10045, 2012.

B. Zhou, M. Wen, and Q. Wu, C-isolated Ag?C?Co sandwich sphere-nanostructures and their high activity catalysis induced by surface plasmon resonance, Nanoscale, vol.5, issue.18, p.8602, 2013.

N. Cao, J. Su, W. Luo, and G. Cheng, Hydrolytic dehydrogenation of ammonia borane and methylamine borane catalyzed by graphene supported Ru@Ni core?shell nanoparticles, International Journal of Hydrogen Energy, vol.39, issue.1, pp.426-435, 2014.

O. Metin, V. Mazumder, S. O?zkar, and S. Sun, Monodisperse Nickel Nanoparticles and Their Catalysis in Hydrolytic Dehydrogenation of Ammonia Borane, Journal of the American Chemical Society, vol.132, issue.5, pp.1468-1469, 2010.

B. Durham, S. R. Wilson, D. J. Hodgson, and T. J. Meyer, Cis-trans photoisomerization in Ru(bpy)2(OH2)22+. Crystal structure of trans-[Ru(bpy)2(OH2)(OH)](ClO4)2, Journal of the American Chemical Society, vol.102, issue.2, pp.600-607, 1980.

E. M. Leitao and I. Manners, Rehydrogenation of Aminoboranes to Amine-Boranes Using H2O: Reaction Scope and Mechanism, European Journal of Inorganic Chemistry, vol.2015, issue.13, pp.2199-2205, 2015.

Z. Xiong, C. K. Yong, G. Wu, P. Chen, W. Shaw et al., High-capacity hydrogen storage in lithium and sodium amidoboranes, Nature Materials, vol.7, issue.2, pp.138-141, 2007.

R. Pineault, Chapitre 5. Influence du contexte et des valeurs sur le système de santé, Comprendre le système de santé pour mieux le gérer, pp.141-151

G. Cuvier, Sur le Megalonyx, animal de la famille des Paresseux, mais de la taille du B?uf, dont les ossemens ont été dé couverts en Virginie en 1796, Recherches sur les ossemens fossiles des quadrupèdes, pp.327-344

H. Castanet, Préface : un réel nouveau produit par le théâtre ? Une thèse, un exemple, Ecritures théâtrales du traumatisme, pp.7-16, 2012.

. Néanmoins and . Dans-des-réactions-comme-le-couplage-de-suzuki-miyaura, Graphique 3.6. En Amérique latine, les résultats en matière de bien-être ont été meilleurs que ne l?aurait laissé escompter le PIB

M. Murata, S. Watanabe, and Y. Masuda, Novel Palladium(0)-Catalyzed Coupling Reaction of Dialkoxyborane with Aryl Halides: Convenient Synthetic Route to Arylboronates, The Journal of Organic Chemistry, vol.62, issue.19, pp.6458-6459, 1997.

P. Sampson, Metal-Catalyzed Cross-Coupling Reactions Edited by F. Diederich (ETH, Zurich) and P. J. Stang (University of Utah). Wiley-VCH: Weinheim. 1998. xxi + 517 pp. $140. ISBN 3-527-29421-X., Journal of the American Chemical Society, vol.120, issue.45, pp.11836-11837, 1998.

L. Euzénat, D. Horhant, C. Brielles, G. Alcaraz, and M. Vaultier, Stereospecific palladium-catalyzed borylation reaction of 1-alkenyl halides with diispropylaminoborane, Journal of Organometallic Chemistry, vol.690, issue.11, pp.2721-2724, 2005.

, Rappels bibliographiques, Labyrinthe, issue.6, p.110, 2000.

H. C. Brown and B. C. Rao, A NEW TECHNIQUE FOR THE CONVERSION OF OLEFINS INTO ORGANOBORANES AND RELATED ALCOHOLS, Journal of the American Chemical Society, vol.78, issue.21, pp.5694-5695, 1956.

N. Miyaura and A. Suzuki, Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds, Chemical Reviews, vol.95, issue.7, pp.2457-2483, 1995.

D. T. Yang and G. W. Kabalka, AN IMPROVED SYNTHESIS OF 5?-CHOLEST-3-ENE, Organic Preparations and Procedures International, vol.9, issue.2, pp.85-87, 1977.

M. D. Shair, T. Yoon, and S. J. Danishefsky, A Remarkable Cross Coupling Reaction to Construct the Enediyne Linkage Relevant to Dynemicin A: Synthesis of the Deprotected ABC System, The Journal of Organic Chemistry, vol.59, issue.14, pp.3755-3757, 1994.

J. P. Das and S. Roy, Catalytic Hunsdiecker Reaction of ?,?-Unsaturated Carboxylic Acids: How Efficient Is the Catalyst?, The Journal of Organic Chemistry, vol.67, issue.22, pp.7861-7864, 2002.

E. Weiss and A. , , p.819, 1983.

S. Bank, Organic syntheses via boranes (Brown, Herbert C.), Journal of Chemical Education, vol.53, issue.5, p.A274, 1976.

M. Murata, S. Watanabe, and Y. Masuda, Rhodium-catalyzed dehydrogenative coupling reaction of vinylarenes with pinacolborane to vinylboronates, Tetrahedron Letters, vol.40, issue.13, pp.2585-2588, 1999.

D. H. Motry, A. G. Brazil, and M. R. Smith, Significance of Borane Tuning in Titanium-Catalyzed Borylation Chemistry?, Journal of the American Chemical Society, vol.119, issue.11, pp.2743-2744, 1997.

S. A. Westcott, T. B. Marder, and R. T. Baker, Transition metal-catalyzed addition of catecholborane to .alpha.-substituted vinylarenes: hydroboration vs dehydrogenative borylation, Organometallics, vol.12, issue.3, pp.975-979, 1993.

R. B. Coapes, F. E. Souza, R. L. Thomas, J. J. Hall, and T. B. Marder, Rhodium catalysed dehydrogenative borylation of vinylarenes and 1,1-disubstituted alkenes without sacrificial hydrogenation?a route to 1,1-disubstituted vinylboronates, Chemical Communications, issue.5, pp.614-615, 2003.

H. Hofmeister, K. Annen, H. Laurent, and R. Wiechert, A Novel Entry to 17?-Bromo- and 17?-Iodoethynyl Steroids, Angewandte Chemie International Edition in English, vol.23, issue.9, pp.727-729, 1984.

M. D. Shair, T. Yoon, and S. J. Danishefsky, A Remarkable Cross Coupling Reaction to Construct the Enediyne Linkage Relevant to Dynemicin A: Synthesis of the Deprotected ABC System, The Journal of Organic Chemistry, vol.59, issue.14, pp.3755-3757, 1994.

P. Michel, D. Gennet, and A. Rassat, A one-pot procedure for the synthesis of alkynes and bromoalkynes from aldehydes, Tetrahedron Letters, vol.40, issue.49, pp.8575-8578, 1999.

F. Diedrich, P. Stang, ;. N. Miyaura, K. Yamada, H. Suginome et al., Metal-Catalyzed Cross-Coupling Reactions, J. Am. Chem. Soc, vol.107, pp.972-980, 1985.

G. Evano, N. Blanchard, and M. Toumi, Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis, Chemical Reviews, vol.108, issue.8, pp.3054-3131, 2008.

F. Monnier and M. Taillefer, Catalytic C?C, C?N, and C?O Ullmann-Type Coupling Reactions, Angewandte Chemie International Edition, vol.48, issue.38, pp.6954-6971, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00413782

Z. Wang, C. Wan, and Y. Wang, Reusable Catalysts for Copper-Mediated Cross-Coupling Reactions under Heterogeneous Conditions, Copper-Mediated Cross-Coupling Reactions, pp.745-784, 2013.

G. Evano, N. Blanchard, ;. T. Wiley, . W. Jeffrey-;-g, T. M. Kabalka et al., Nucl. Med. Biol, vol.27, pp.279-287, 1998.

D. P. Ojha and K. R. Prabhu, Regioselective Synthesis of Vinyl Halides, Vinyl Sulfones, and Alkynes: A Tandem Intermolecular Nucleophilic and Electrophilic Vinylation of Tosylhydrazones, Organic Letters, vol.17, issue.1, pp.18-21, 2014.

P. Pawlu?, G. Hreczycho, J. Szudkowska, M. Kubicki, and B. Marciniec, Org. Lett, vol.11, pp.3390-3393, 2009.

A. Suzuki and Y. Yamamoto, Cross-coupling Reactions of Organoboranes: An Easy Method for C?C Bonding, Chemistry Letters, vol.40, issue.9, pp.894-901, 2011.

J. A. Sinclair, G. A. Molander, and H. C. Brown, Conjugate addition of B-1-alkynyl-9-borabicyclo[3.3.1]-nonanes to .alpha.,.beta.-unsaturated ketones. A convenient synthesis of .gamma.,.delta.-acetylenic ketones, Journal of the American Chemical Society, vol.99, issue.3, pp.954-956, 1977.

J. Soulie and P. Cadiot, Bull. Soc. Chim, vol.75, issue.7-8, p.3846, 1966.

H. C. Brown and M. Srebnik, Organoboranes. 50. Preparation and characterization of organyl-1-alkynylborinic esters, Organometallics, vol.6, issue.3, pp.629-631, 1987.

H. C. Brown, N. G. Bhat, and M. Srebnik, A simple, general synthesis of 1-alkynyldiisopropoxyboranes, Tetrahedron Letters, vol.29, issue.22, pp.2631-2634, 1988.

J. Jiao and Y. Nishihara, Alkynylboron compounds in organic synthesis, Journal of Organometallic Chemistry, vol.721-722, pp.3-16, 2012.

J. J. Eisch, Boron?Carbon Multiple Bonds, Advances in Organometallic Chemistry, pp.355-391, 1996.

L. Deloux and M. Srebnik, Preparation of (Z)-1-Alkenyl Dioxaborolanes by Hydrolysis of Boryl Zirconocene 1,1-Dimetalloalkenes, The Journal of Organic Chemistry, vol.59, issue.22, pp.6871-6873, 1994.

D. A. Singleton and S. Leung, In situ formation of alkenyl- and alkynylboranes for Diels?Alder reactions by boron?silicon exchange with alkenyl- and alkynylsilanes, Journal of Organometallic Chemistry, vol.544, issue.2, pp.157-161, 1997.

H. C. Brown, G. A. Molander, S. M. Singh, and U. S. Racherla, Organoboranes. 38. A facile and highly efficient addition of B-1-alkynyl-9-borabicyclo[3.3.1]nonanes to aldehydes and ketones: an exceptionally chemoselective synthesis of propargylic alcohols, The Journal of Organic Chemistry, vol.50, issue.10, pp.1577-1582, 1985.

E. J. Corey and K. A. Cimprich, Highly Enantioselective Alkynylation of Aldehydes Promoted by Chiral Oxazaborolidines, Journal of the American Chemical Society, vol.116, issue.7, pp.3151-3152, 1994.

S. Kim, C. M. Cho, and J. Yoon, Reaction ofN-Aziridinylimines with Alkynylborane Reagents. A New Route to Allenes from Aldehydes and Ketones, The Journal of Organic Chemistry, vol.61, issue.17, pp.6018-6020, 1996.

G. A. Molander and H. C. Brown, Reaction of 9-(1-Alkynyl)-9-borabicyclo[3.3.1]nonanes with Isocyanates, Synthesis, vol.1979, issue.02, pp.104-105, 1979.

M. Yamaguchi, Y. Nobayashi, and I. Hirao, A ring opening reaction of oxetanes with lithium acetylides promoted by boron trifluoride etherate, Tetrahedron, vol.40, issue.21, pp.4261-4266, 1984.

T. N. Nguyen and J. A. May, Enantioselective organocatalytic conjugate addition of organoboron nucleophiles, Tetrahedron Letters, vol.58, issue.16, pp.1535-1544, 2017.

K. Jouvin and G. Evano, Beyond Ullmann-Goldberg Chemistry: Vinylation, Alkynylation, and Allenylation of Heteronucleophiles, Copper-Mediated Cross-Coupling Reactions, pp.187-238, 2013.

D. E. Kaufmann, D. S. Matteson, and E. , Product Subclass 16: Phosphinoboranes and Borane?Phosphine Complexes, Category 1, Organometallics, vol.6, pp.3-16, 2005.

M. Vaultier and G. Alcaraz, Vinylboranes, ChemInform, vol.37, issue.29, pp.721-853, 2006.

H. C. Brown and M. Srebnik, Organoboranes. 50. Preparation and characterization of organyl-1-alkynylborinic esters, Organometallics, vol.6, issue.3, pp.629-631, 1987.

S. Danis, 2. La BPI ou l?espace revisité, Mettre en ?uvre un plan de classement, pp.164-181
URL : https://hal.archives-ouvertes.fr/hal-02394637

H. Nimoun, Activation et transfert de l'oxygène moléculaire catalysés par les complexes des métaux de transition, Revue de l'Institut Français du Pétrole, vol.33, issue.2, pp.259-298, 1978.

J. H. Basso, C. Calleri, and R. Luft, Anisotropie et polarisabilité optiques des liaisons chimiques, Journal de Chimie Physique, vol.75, pp.741-746, 1978.

, Graphique 14.3. Bien que les femmes constituent souvent plus de la moitié des salariés dans l?administration centrale, elles sont généralement sous-représentées aux plus hauts échelons

A. Le bouëdec, La construction d?un discours organisationnel par le Message Management, Revue française des sciences de l?information et de la communication, issue.9, 2016.

L. V. Travaux-d'o, Graphique 6.11. Les élèves de 15 ans dont les parents ne sont pas diplômés du secondaire ont de moins bons résultats que les autres

H. Chen, S. Schlecht, T. C. Semple, and J. F. Hartwig, Thermal, Catalytic, Regiospecific Functionalization of Alkanes, Science, vol.287, issue.5460, pp.1995-1997, 2000.

T. Ishiyama, K. Ishida, J. Takagi, and N. Miyaura, Palladium-Catalyzed Benzylic C?H Borylation of Alkylbenzenes with Bis(pinacolato)diboron or Pinacolborane, Chemistry Letters, vol.30, issue.11, pp.1082-1083, 2001.

V. J. Olsson and K. J. Szabó, Selective One-Pot Carbon?Carbon Bond Formation by Catalytic Boronation of Unactivated Cycloalkenes and Subsequent Coupling, Angewandte Chemie International Edition, vol.46, issue.36, pp.6891-6893, 2007.

J. M. Brown and G. C. Lloyd-jones, Vinylborane Formation in Rhodium-Catalyzed Hydroboration of Vinylarenes. Mechanism versus Borane Structure and Relationship to Silation, Journal of the American Chemical Society, vol.116, issue.3, pp.866-878, 1994.

R. B. Coapes, F. E. Souza, R. L. Thomas, J. J. Hall, and T. B. Marder, Rhodium catalysed dehydrogenative borylation of vinylarenes and 1,1-disubstituted alkenes without sacrificial hydrogenation?a route to 1,1-disubstituted vinylboronates, Chemical Communications, issue.5, pp.614-615, 2003.

N. I. Lee, J. Zhou, and O. V. Ozerov, Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium, Journal of the American Chemical Society, vol.135, issue.9, pp.3560-3566, 2013.

K. Ziegler, E. Holzkamp, H. Breil, and H. Martin, Polymerisation von Äthylen und anderen Olefinen, Angewandte Chemie, vol.67, issue.16, pp.426-426, 1955.

G. Natta and A. , Von der stereospezifischen Polymerisation zur asymmetrischen autokatalytischen Synthese von Makromolekülen Nobel-Vortrag am 12. Dezember 1963, Angewandte Chemie, vol.76, issue.13, pp.553-566, 1964.

T. Mukaiyama, T. Izawa, and K. Saigo, REACTION OF ENOL ACETATE WITH ACETAL AND CARBONYL COMPOUND IN THE PRESENCE OF LEWIS ACID, Chemistry Letters, vol.3, issue.4, pp.323-326, 1974.

S. Bontemps, G. Bouhadir, K. Miqueu, and D. Bourissou, On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligandso-R2P(Ph)BR?2, Journal of the American Chemical Society, vol.128, issue.37, pp.12056-12057, 2006.

G. C. Welch, R. R. Juan, J. D. Masuda, and D. W. Stephan, Reversible, Metal-Free Hydrogen Activation, Science, vol.314, issue.5802, pp.1124-1126, 2006.

D. W. Stephan, Frustrated Lewis Pairs: From Concept to Catalysis, Accounts of Chemical Research, vol.48, issue.2, pp.306-316, 2014.

G. Bouhadir and D. Bourissou, Complexes of ambiphilic ligands: reactivity and catalytic applications, Chemical Society Reviews, vol.45, issue.4, pp.1065-1079, 2016.

M. A. Nesbit, D. L. Suess, and J. C. Peters, E?H Bond Activations and Hydrosilylation Catalysis with Iron and Cobalt Metalloboranes, Organometallics, vol.34, issue.19, pp.4741-4752, 2015.

F. Inagaki, C. Matsumoto, Y. Okada, N. Maruyama, and C. Mukai, Air-Stable Cationic Gold(I) Catalyst Featuring a Z-Type Ligand: Promoting Enyne Cyclizations, Angewandte Chemie International Edition, vol.54, issue.3, pp.818-822, 2014.

T. Schindler, M. Lux, M. Peters, L. T. Scharf, H. Osseili et al., Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand, Organometallics, vol.34, issue.10, pp.1978-1984, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01968865

A. C. Mcquilken, Q. M. Dao, A. J. Cardenas, J. A. Bertke, S. Grimme et al., A Frustrated and Confused Lewis Pair, Angewandte Chemie, vol.128, issue.46, pp.14547-14551, 2016.

T. H. Grimme and . Warren, Angew. Chemie Int. Ed, vol.55, pp.14335-14339, 2016.

F. Fontaine and É. Rochette, Ambiphilic Molecules: From Organometallic Curiosity to Metal-Free Catalysts, Accounts of Chemical Research, vol.51, issue.2, pp.454-464, 2018.

A. R. Jupp and D. W. Stephan, New Directions for Frustrated Lewis Pair Chemistry, Trends in Chemistry, vol.1, issue.1, pp.35-48, 2019.

, Les tendances technologiques, éducatives et des politiques publiques ont été les principaux ressorts des variations des inégalités salariales et de l'emploi dans la zone OCDE, L'une des voies classiques de synthèse des acides boriniques symétriques consiste à faire réagir des dérivés organométalliques (organolithien / organomagnésien) avec des électrophiles borés (alkoxyboranes / halogénoboranes), 2012.

, Le nombre et le pourcentage d'immigrés varient entre les pays partenaires du projet, p.265, 2018.

, Les salaires sont plus sensibles au cycle dans le cas des nouvelles embauches que dans celui des travailleurs déjà en poste, vol.89, 2014.

, Coût associé à un (faible) besoin de prise en charge à partir de 65 ans, Synthèse des acides boriniques dérivés du 2-aminoéthanol via un organomagnésien, vol.90, 2013.

N. G. Buu-hoï, Une méthode générale de synthèse des acides gras supérieurs linéaires ou ramifiés, Recueil des Travaux Chimiques des Pays-Bas, vol.72, issue.1, pp.84-87, 2010.

A. Hofer, G. Kovacs, A. Zappatini, M. Leuenberger, M. A. Hediger et al., Design, synthesis and pharmacological characterization of analogs of 2-aminoethyl diphenylborinate (2-APB), a known store-operated calcium channel blocker, for inhibition of TRPV6-mediated calcium transport, Bioorganic & Medicinal Chemistry, vol.21, issue.11, pp.3202-3213, 2013.

A. Meudt, M. Erbes, and K. Forstinger, Germany: Clariant ? masterbatch, Focus on Pigments, vol.2005, issue.7, p.5, 2005.

X. Chen, H. Ke, Y. Chen, C. Guan, and G. Zou, Cross-Coupling of Diarylborinic Acids and Anhydrides with Arylhalides Catalyzed by a Phosphite/N-Heterocyclic Carbene Co-supported Palladium Catalyst System, The Journal of Organic Chemistry, vol.77, issue.17, pp.7572-7578, 2012.

M. G. Chudzinski, Y. Chi, and M. S. Taylor, Borinic Acids: A Neglected Class of Organoboron Compounds for Recognition of Diols in Aqueous Solution, Australian Journal of Chemistry, vol.64, issue.11, p.1466, 2011.

I. V. Chapitre, Synthèse de ligands phosphine-borane ambiphiles

H. Gilman and L. O. Moore, Some Studies on the Preparation of Arylboronic Acids1, Journal of the American Chemical Society, vol.80, issue.14, pp.3609-3611, 1958.

H. C. Brown, M. Srebnik, and T. E. Cole, Organoboranes. 48. Improved procedures for the preparation of boronic and borinic esters, Organometallics, vol.5, issue.11, pp.2300-2303, 1986.

W. Seaman and J. R. Johnson, DERIVATIVES OF PHENYLBORIC ACID, THEIR PREPARATION AND ACTION UPON BACTERIA, Journal of the American Chemical Society, vol.53, issue.2, pp.711-723, 1931.

F. R. Bean and J. R. Johnson, DERIVATIVES OF PHENYLBORIC ACID, THEIR PREPARATION AND ACTION UPON BACTERIA. II. HYDROXYPHENYLBORIC ACIDS1, Journal of the American Chemical Society, vol.54, issue.11, pp.4415-4425, 1932.

D. E. Cladingboel, A Large, Laboratory-Scale Synthesis of [4-(2-(2H)-Tetrahydropyranyloxy)phenyl]boronic Acid, Organic Process Research & Development, vol.4, issue.3, pp.153-155, 2000.

R. T. Hawkins and D. B. Stroup, Some extensions of the ortho lithiation reaction, The Journal of Organic Chemistry, vol.34, issue.4, pp.1173-1174, 1969.

M. Lauer and G. Wulff, Arylboronic acids with intramolecular B?N interaction: convenient synthesis through ortho-lithiation of substituted benzylamines, Journal of Organometallic Chemistry, vol.256, issue.1, pp.1-9, 1983.

L. Yuxin, J. Milo, H. L. Lawrence, and . Jack, Reviews and accounts, vol.1, pp.135-153, 2013.

R. D. Larsen, A. O. King, C. Y. Chen, E. G. Corley, B. S. Foster et al., ChemInform Abstract: Efficient Synthesis of Losartan, a Nonpeptide Angiotensin II Receptor Antagonist., ChemInform, vol.26, issue.16, pp.no-no, 1995.

M. Tschaen, J. Org. Chem, vol.59, pp.6391-6394, 1994.

A. Antoft-finch, T. Blackburn, and V. Snieckus, N,N-DiethylO-Carbamate: Directed Metalation Group and Orthogonal Suzuki?Miyaura Cross-Coupling Partner, Journal of the American Chemical Society, vol.131, issue.49, pp.17750-17752, 2009.

R. C. Larock, Organomercurials in organic synthesis, Tetrahedron, vol.38, issue.12, pp.1713-1754, 1982.

S. W. Breuer, F. G. Thorpe, and J. C. Podestá, The reaction of organomercurials with borane: A synthetic route to arylboronic acids, Tetrahedron Letters, vol.15, issue.42, pp.3719-3720, 1974.

W. Haubold, J. Herdtle, W. Gollinger, and W. Einholz, Darstellung von arylhalogenboranen, Journal of Organometallic Chemistry, vol.315, issue.1, pp.1-8, 1986.

Z. Zhao and V. Snieckus, DirectedorthoMetalation-Based Methodology. Halo-, Nitroso-, and Boro-Inducedipso-Desilylation. Link to anin situSuzuki Reaction?, Organic Letters, vol.7, issue.13, pp.2523-2526, 2005.

T. Ishiyama, M. Murata, and N. Miyaura, Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters, The Journal of Organic Chemistry, vol.60, issue.23, pp.7508-7510, 1995.

T. T. Dang, Y. Zhu, S. C. Ghosh, A. Chen, C. L. Chai et al., Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5, Chemical Communications, vol.48, issue.12, p.1805, 2012.

L. Euzénat, D. Horhant, C. Brielles, G. Alcaraz, and M. Vaultier, Stereospecific palladium-catalyzed borylation reaction of 1-alkenyl halides with diispropylaminoborane, Journal of Organometallic Chemistry, vol.690, issue.11, pp.2721-2724, 2005.

H. D. Guerrand, L. D. Marciasini, M. Jousseaume, M. Vaultier, and M. Pucheault, Borylation of Unactivated Aryl Chlorides under Mild Conditions by Using Diisopropylaminoborane as a Borylating Reagent, Chemistry - A European Journal, vol.20, issue.19, pp.5573-5579, 2014.

L. D. Marciasini, N. Richy, M. Vaultier, and M. Pucheault, Iron-Catalysed Borylation of Arenediazonium Salts to Give Access to Arylboron DerivativesviaAryl(amino)boranes at Room Temperature, Advanced Synthesis & Catalysis, vol.355, issue.6, pp.1083-1088, 2013.

G. J. Mckiernan and R. C. Hartley, Boronate Titanium Alkylidene Reagents for Diversity-Based Synthesis of Benzofurans, Organic Letters, vol.5, issue.23, pp.4389-4392, 2003.

M. Murata, T. Oyama, S. Watanabe, and Y. Masuda, Palladium-Catalyzed Borylation of Aryl Halides or Triflates with Dialkoxyborane: A Novel and Facile Synthetic Route to Arylboronates, The Journal of Organic Chemistry, vol.65, issue.1, pp.164-168, 2000.

O. Baudoin, D. Guénard, and F. Guéritte, Palladium-Catalyzed Borylation of Ortho-Substituted Phenyl Halides and Application to the One-Pot Synthesis of 2,2?-Disubstituted Biphenyls, The Journal of Organic Chemistry, vol.65, issue.26, pp.9268-9271, 2000.

T. Ishiyama, K. Ishida, and N. Miyaura, Synthesis of pinacol arylboronates via cross-coupling reaction of bis(pinacolato)diboron with chloroarenes catalyzed by palladium(0)?tricyclohexylphosphine complexes, Tetrahedron, vol.57, issue.49, pp.9813-9816, 2001.

S. D. Ramgren, L. Hie, Y. Ye, and N. K. Garg, Nickel-Catalyzed Suzuki?Miyaura Couplings in Green Solvents, Organic Letters, vol.15, issue.15, pp.3950-3953, 2013.

D. A. Wilson, C. J. Wilson, C. Moldoveanu, A. Resmerita, P. Corcoran et al., Neopentylglycolborylation of Aryl Mesylates and Tosylates Catalyzed by Ni-Based Mixed-Ligand Systems Activated with Zn, Journal of the American Chemical Society, vol.132, issue.6, pp.1800-1801, 2010.

C. Kleeberg, L. Dang, Z. Lin, and T. B. Marder, A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents, Angewandte Chemie International Edition, vol.48, issue.29, pp.5350-5354, 2009.

I. A. Mkhalid, J. H. Barnard, T. B. Marder, J. M. Murphy, and J. F. Hartwig, C?H Activation for the Construction of C?B Bonds, Chemical Reviews, vol.110, issue.2, pp.890-931, 2010.

C. N. Iverson and M. R. Smith, Stoichiometric and Catalytic B?C Bond Formation from Unactivated Hydrocarbons and Boranes, Journal of the American Chemical Society, vol.121, issue.33, pp.7696-7697, 1999.

J. Cho, C. N. Iverson, and M. R. Smith, Steric and Chelate Directing Effects in Aromatic Borylation, Journal of the American Chemical Society, vol.122, issue.51, pp.12868-12869, 2000.

H. Chen, S. Schlecht, T. C. Semple, and J. F. Hartwig, Thermal, Catalytic, Regiospecific Functionalization of Alkanes, Science, vol.287, issue.5460, pp.1995-1997, 2000.

T. Ishiyama, J. Takagi, K. Ishida, N. Miyaura, N. R. Anastasi et al., Mild Iridium-Catalyzed Borylation of Arenes. High Turnover Numbers, Room Temperature Reactions, and Isolation of a Potential Intermediate, Journal of the American Chemical Society, vol.124, issue.3, pp.390-391, 2002.

S. Shimada, A. S. Batsanov, J. A. Howard, and T. B. Marder, Formation of Aryl- and Benzylboronate Esters by Rhodium-Catalyzed C?H Bond Functionalization with Pinacolborane, Angewandte Chemie International Edition, vol.40, issue.11, pp.2168-2171, 2001.

G. A. Chotana, M. A. Rak, and M. R. Smith, Sterically Directed Functionalization of Aromatic C?H Bonds: Selective Borylation Ortho to Cyano Groups in Arenes and Heterocycles, Journal of the American Chemical Society, vol.127, issue.30, pp.10539-10544, 2005.

T. E. Hurst, T. K. Macklin, M. Becker, E. Hartmann, W. Kügel et al., Iridium-Catalyzed C?H Activation versus DirectedorthoMetalation: Complementary Borylation of Aromatics and Heteroaromatics, Chemistry - A European Journal, vol.16, issue.27, pp.8155-8161, 2010.

, Graphique 3.4 L'alignement des salaires et des durées de formation des enseignants du préprimaire et du primaire est de plus en plus répandu à travers les pays (2013), L'acide boronique 156 attendu n'a pas été obtenu dans les conditions réactionnelles

, Tableau 3.1. Exemples d?estimation permis par permis de la contribution des migrants temporaires de travail en équivalent année pleine

A. Goulet and I. Giroux, Les comportements violents: comparaison des couples selon que l'homme est perçu ou non par sa conjointe comme un joueur problèmatique, Journal of Gambling Issues, issue.30, p.73, 2015.

F. Spitz, ETUDE DES BIOTOPES DE CIRCULATION DE QUELQUES ESPECES DE MICROMAMMIFERES PAR LA METHODE DU CARRE DE PIEGEAGE, Mammalia, vol.29, issue.3, 1965.

A. Sean and M. Lequan, Échange lithium-halogène dans la réaction de condensation du méthyl- ?-naphtyl-phényl-germyl-lithium avec les bromures de type propargylique, Journal of Organometallic Chemistry, vol.42, issue.1, pp.C3-C4, 1972.

, Les capacités ont été sous-utilisées dans de nombreux pays en 2012, en partie à cause d?une demande faible, Les conditions d'obtention du produit ont été optimisées par rapport à celles utilisées dans la partie précédente

N. Lernout, Utilisation du schéma de l'organisation du milieu humain et plus particulièrement du niveau de l'ambiance, en thérapie, Thérapie Familiale, vol.27, issue.2, p.193, 2006.

R. Kuhn, Moleculare Asymmetfie in Stereochemie, Franz Deutike, pp.803-824, 1933.

G. H. Christie and J. Kenner, LXXI.?The molecular configurations of polynuclear aromatic compounds. Part I. The resolution of ?-6 : 6?-dinitro- and 4 : 6 : 4? : 6?-tetranitro-diphenic acids into optically active components, J. Chem. Soc., Trans., vol.121, issue.0, pp.614-620, 1922.

R. Adams and H. C. Yuan, The Stereochemistry of Diphenyls and Analogous Compounds., Chemical Reviews, vol.12, issue.2, pp.261-338, 1933.

G. Bringmann, A. J. Price-mortimer, P. A. Keller, M. J. Gresser, J. Garner et al., Atroposelective Synthesis of Axially Chiral Biaryl Compounds, Angewandte Chemie International Edition, vol.44, issue.34, pp.5384-5427, 2005.

K. Oki-;-allinger, N. Eliel, E. E. Wilen, and S. H. Wiley, Topics in Stereochemistry, Topics in Stereochemistry, vol.14, pp.1-76, 1983.

K. R. Wilson and R. E. Pincock, Thermally induced resolution of racemic 1,1'-binaphthyl in the solid state, Journal of the American Chemical Society, vol.97, issue.6, pp.1474-1478, 1975.

K. Mislow and A. , Die absolute Konfiguration der atropisomeren Diaryl-Verbindungen, Angewandte Chemie, vol.70, issue.22-23, pp.683-689, 1958.

V. Chapitre, Chapitre XII. Essai De Synthèse, Le pouvoir et les groupes de pression, pp.266-280, 1971.

M. B. Smith, Advertisement, Journal of Natural Products, vol.47, issue.5, pp.911-911, 1984.

R. Adams, R. C. Morris, D. J. Butterbaugh, and E. C. Kirkpatrick, Structure of Gossypol.1XIV. Apogossypolic Acid, Journal of the American Chemical Society, vol.60, issue.9, pp.2191-2193, 1938.

S. M. Kupchan, R. W. Britton, M. F. Ziegler, C. J. Gilmore, R. J. Restivo et al., Tumor inhibitors. LXXXX. Steganacin and steganangin, novel antileukemic lignan lactones from Steganotaenia araliacea, Journal of the American Chemical Society, vol.95, issue.4, pp.1335-1336, 1973.

:. M. Synthèse-Énantiosélective, F. Taafrout, J. Rouessac, and . Robin, Tetrahedron Lett, vol.24, pp.2983-2986, 1983.

J. M. Brunel, BINOL: A Versatile Chiral Reagent, Chemical Reviews, vol.105, issue.3, pp.857-898, 2005.

R. Schmid, M. Cereghetti, B. Heiser, P. Schönholzer, and H. Hansen, Axially Dissymmetric Bis(triaryl)phosphines in the Biphenyl series: Synthesis of (6,6?-dimethylbiphenyl-2,2?-diyl)bis(diphenylphosphine) (?BIPHEMP?) and analogues, and their use in Rh(I)-catalyzed asymmetric isomerizations ofN,N-diethylnerylamine, Helvetica Chimica Acta, vol.71, issue.4, pp.897-929, 1988.

O. D. Lucchi, Pure & Appl. Chem, vol.40, pp.553-556, 1996.

V. Chapitre, Synthèse d'aminoboranes atropoisomères -Etude de la chiralité axiale C-B Schéma 113 : Cyclisation radicalaire via l'utilisation d

, État de la Population Mondiale 2009, 2010.

, Un exemple intéressant de construction par soudure, La Pratique des Industries Mécaniques, vol.14, issue.8, pp.324-324, 1931.

. Schéma, Réaction d'un électrophile sur un atropoisomère -Mise en évidence de l'intermédiaire énolate

T. Kawamoto, M. Tomishima, J. Kunitomo, F. Yoneda, and J. Hayami, First example of ?diastereotopic face activation? and chiral recognition without metal assistance. A novel 5-deazaflavin enzyme model., Tetrahedron Letters, vol.33, issue.47, pp.7173-7176, 1992.

T. Kawamoto, M. Tomishima, F. Yoneda, and J. Hayami, Diastereoface differentiating ?(net) hydride transfer? in novel 5-deazaflavins modified at pyrimidine ring, Tetrahedron Letters, vol.33, issue.22, pp.3173-3176, 1992.

T. Kawamoto, T. Taga, K. Bessho, F. Yoneda, and J. Hayami, Stereochemistry of asymmetric ?(net) hydride transfer? in an intercoenzyme model reaction system, Tetrahedron Letters, vol.35, issue.46, pp.8631-8634, 1994.

A. Honda, K. M. Waltz, P. J. Carroll, and P. J. Walsh, Atropisomeric amides: Achiral ligands with chiral conformations, Chirality, vol.15, issue.7, pp.615-621, 2003.

A. Honda, K. M. Waltz, P. J. Carroll, P. J. Walsh, ;. E. Kumarasamy et al., Chem. Rev, vol.15, pp.11239-11300, 2003.

B. M. Trost and D. L. Van-vranken, Asymmetric Transition Metal-Catalyzed Allylic Alkylations, Chemical Reviews, vol.96, issue.1, pp.395-422, 1996.

X. Dai and S. Virgil, Asymmetric allylic alkylation catalyzed by palladium complexes with atropisomeric quinazolinone phosphine ligands, Tetrahedron Letters, vol.40, issue.7, pp.1245-1248, 1999.

F. Wang, S. Li, M. Qu, M. Zhao, L. Liu et al., A highly efficient kinetic resolution of Morita?Baylis?Hillman adducts achieved by N?Ar axially chiral Pd-complexes catalyzed asymmetric allylation, Chemical Communications, vol.47, issue.48, p.12813, 2011.

T. Bach, J. Schröder, and K. Harms, Diastereoselective photocycloaddition of an axial chiral enamide, Tetrahedron Letters, vol.40, issue.51, pp.9003-9004, 1999.

C. Müller and T. Bach, Chirality Control in Photochemical Reactions: Enantioselective Formation of Complex Photoproducts in Solution, Australian Journal of Chemistry, vol.61, issue.8, p.557, 2008.

B. C. Pemberton, R. Raghunathan, S. Volla, and J. Sivaguru, From Containers to Catalysts: Supramolecular Catalysis within Cucurbiturils, Chemistry - A European Journal, vol.18, issue.39, pp.12178-12190, 2012.

V. Chapitre, Chapitre XII. Essai De Synthèse, Le pouvoir et les groupes de pression, pp.266-280, 1971.

, 1.56 Quatre premiers pays en termes de nombre de publications parmi les 10 % les plus citées, par discipline, 2003-12, Les anilides furent parmi les premiers systèmes employés pour des applications dans des réactions atroposélectives, vol.117

N. S. L'équipe-de, Simpkins a réalisé la synthèse diastéréosélective d'atropoisomères par dédoublement cinétique d'un racémique (Schéma 118). 338 Le traitement par une base chirale lithiée 175 suivi d'un piégeage électrophile avec du iodométhane a en effet permis la récupération du composé 176 avec un excès énantiomérique de 88%

J. Dumas, 5. Transmettre à la fois une information et un message, Séduire par les mots, pp.131-163
URL : https://hal.archives-ouvertes.fr/hal-01925579

D. P. Curran, H. Qi, S. J. Geib, and N. C. Demello, Atroposelective Thermal Reactions of Axially Twisted Amides and Imides, Journal of the American Chemical Society, vol.116, issue.7, pp.3131-3132, 1994.

A. D. Hughes, D. A. Price, O. Shishkin, and N. S. Simpkins, Diastereoselective enolate chemistry using atropisomeric amide, Tetrahedron Letters, vol.37, issue.42, pp.7607-7610, 1996.

H. H. Sun, C. J. Barrow, and R. Cooper, Benzomalvin D, a New 1,4-Benzodiazepine Atropisomer, Journal of Natural Products, vol.58, issue.10, pp.1575-1580, 1995.

X. Dai, A. Wong, and S. C. Virgil, Synthesis and Resolution of Quinazolinone Atropisomeric Phosphine Ligands?,?, The Journal of Organic Chemistry, vol.63, issue.8, pp.2597-2600, 1998.

V. Chapitre, Chapitre XII. Essai De Synthèse, Le pouvoir et les groupes de pression, pp.266-280, 1971.

, Établir la séquence des activités en fonction des modifications comportementales souhaitées, Le plan de communication, pp.133-146, 2004.

, Valeur ajoutée nominale par salarié dans l'agriculture rapportée à la valeur ajoutée nominale par salarié dans l'ensemble de l'économie, en 2010, J. Clayden, vol.343, 2013.

, Une approche de la prévision du choix modal basée sur l'analyse du comportement des usagers. Transpn Res., Transportation Research, vol.3, issue.4, p.vii, 1969.

, Enantioselective Iridium-Catalyzed Hydrogenation of Keto Amides to Hydroxy Amides, Synthèse énantiosélective d'amides atropoisomères, vol.121

, Que sont les accords OTC et SPS de l?OMC et quelles sont les principales différences entre eux?, Les rendements et excès énantiomériques sont très dépendants du substrat et compris entre 5% -62%, 2011.

C. Biondi, Je est un autre. Pour une identité-monde, sous la direction de Michel Le Bris et Jean Rouaud, avec le concours de Nathalie Skowronek, Studi Francesi, vol.122, issue.166 (I | LVI), pp.191-192, 2012.

T. H. Siddall and R. H. Garner, Can. J. Chem, p.2387, 1966.

P. Bowles, J. Clayden, and M. Tomkinson, Diastereoisomeric atropisomers from the addition of lithiated N,N-dialkyl-l-naphthamides to aldehydes, Tetrahedron Letters, vol.36, issue.50, pp.9219-9222, 1995.

P. Beak, A. Basu, D. J. Gallagher, Y. S. Park, and S. Thayumanavan, Regioselective, Diastereoselective, and Enantioselective Lithiation?Substitution Sequences: Reaction Pathways and Synthetic Applications, Accounts of Chemical Research, vol.29, issue.11, pp.552-560, 1996.

D. P. Curran, H. Qi, S. J. Geib, and N. C. Demello, Atroposelective Thermal Reactions of Axially Twisted Amides and Imides, Journal of the American Chemical Society, vol.116, issue.7, pp.3131-3132, 1994.

J. Clayden, Atropisomers and near-atropisomers: achieving stereoselectivity by exploiting the conformational preferences of aromatic amides, Chemical Communications, issue.2, p.127, 2004.

V. Chapitre, Chapitre XII. Essai De Synthèse, Le pouvoir et les groupes de pression, pp.266-280, 1971.

L. Flem, Perdre, créer : la littérature existe parce que la réalité ne nous suffit pas, Ruptures, p.107, 2013.

L. Chardonnens and E. Horváth, Sur les dérivés de la fluorénone VI Les acides bromo-3-fluorénonecarboxylique-2 et bromo-2-fluorénonecarboxylique-3 et la bromo-3-méthyl-4-fluorénone, Helvetica Chimica Acta, vol.56, issue.8, pp.3039-3044, 1973.

, Les capacités de recherche du secteur privé ont été relativement préservées, vol.128, 2015.

N. P. Ramzaeva, M. Y. Lidak, Y. S. Gol'dberg, and M. V. Shimanskaya, ChemInform Abstract: Alkylation of 6-Substituted Purines by ?-Bromo-?-haloalkanes Under Interphase Catalysis Conditions., ChemInform, vol.19, issue.37, 1988.

, Graphique 7. Distribution des scores en littératie des immigrés et des personnes nées dans le pays ayant un niveau d'éducation tertiaire, âgés de 16 à 64 ans, selon le lieu où le plus haut diplôme a été obtenu

, Articles faites par le roy de France, avec ceux de la religion reforme?e

M. Tremblay, La Vérification générale du Québec:, L'État québécois, vol.129, pp.405-428, 2019.

M. E. Burin, V. A. Ilichev, A. P. Pushkarev, D. L. Vorozhtsov, S. Y. Ketkov et al., Synthesis and luminescence properties of lithium, zinc and scandium 1-(2-pyridyl)naphtholates, Organic Electronics, vol.13, issue.12, pp.3203-3210, 2012.

K. Z. ?a?czkowski, D. Garci?a, D. Pen?a, A. Cobas, D. Pe?rez et al., Highly Selective Insertion of Arynes into a C(sp)?O(sp3) ? Bond, Organic Letters, vol.13, issue.5, pp.960-963, 2011.

V. Chapitre, Chapitre XII. Essai De Synthèse, Le pouvoir et les groupes de pression, pp.266-280, 1971.

, Rendement privé net et rendement public net de l'obtention d'un diplôme de l'enseignement tertiaire chez les individus de sexe masculin (2009), 2013.

, Graphique 1.9. En 2007, les dépenses au titre des programmes du marché du travail ont été relativement faibles dans la plupart des pays où le chômage a ensuite fortement augmenté, vol.130

J. Roussos, Expert deference as a belief revision schema, Synthese, vol.130, 2020.

, Graphique 4.6. Jusqu?à présent, les réductions d?émission ont été principalement réalisées dans le secteur de l?électricité, Pour obtenir le 2-benzyl-1-bromonaphtalène 205 deux étapes synthétiques ont été nécessaires

P. Gouilly, Le congrès de la WCPT est terminé ! Vive le prochain WCPT !!, Kinésithérapie, la Revue, vol.15, issue.162, p.1, 2015.

J. Roussos, Expert deference as a belief revision schema, Synthese, vol.131, 2020.

J. Fayn and A. Cambon, Addition de N-methyl nitrone sur les F-alkyl-1 bromo-1 ethene une cycloaddition dipolaire-1,3 en deux etapes, Journal of Fluorine Chemistry, vol.47, issue.1, pp.71-77, 1990.

, Transitions de phase destructive et non destructive dans le cristal moleculaire bromo-2 naphtalene, Solid State Communications, vol.36, issue.12, p.iv, 1980.

S. Huang, L. Kötzner, C. K. De, and B. List, Catalytic Asymmetric Dearomatizing Redox Cross Coupling of Ketones with Aryl Hydrazines Giving 1,4-Diketones, Journal of the American Chemical Society, vol.137, issue.10, pp.3446-3449, 2015.

T. Peez, V. Schmalz, K. Harms, and U. Koert, Synthesis of Naphthocyclobutenes from ?-Naphthyl Acrylates by Visible-Light Energy-Transfer Catalysis, Organic Letters, vol.21, issue.11, pp.4365-4369, 2019.

L. J. Van-der-boon, L. Van-gelderen, T. R. De-groot, M. Lutz, J. C. Slootweg et al., Chiral Control in Pentacoordinate Systems: The Case of Organosilicates, Inorganic Chemistry, vol.57, issue.20, pp.12697-12708, 2018.

S. Xu, Y. Zhang, B. Li, and S. Liu, Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine?Pd Complex, Journal of the American Chemical Society, vol.138, issue.44, pp.14566-14569, 2016.

, Les tarifs d'achat ont été le moteur de la croissance spectaculaire du solaire, 2012.

B. Carboni and F. Carreaux, Borane?Amine Complexes by Halogenation of Borane Complexes, Boron Compounds, p.1, 2005.

, Carte des Îles de Pong-hou suivant le point sur le quel ont été faites les Cartes de la Chine et de la Tartarie par l'Ordre et aux frais de l'Empereur, Huit complexes différents possédant des amines secondaires ont été obtenus en suivant le protocole classique NaBH4/H2SO4/amine, vol.356

B. Sansal and D. T. Analis, Les « francofffonies ! » à Liré : l?histoire de deux rencontres avec la langue française, Le français : des mots de chacun, une langue pour tous, pp.321-329

B. L. Booth, N. J. Lawrence, R. G. Pritchard, and H. S. Rashid, Synthesis and X-ray crystal structure of (1S,3R,4S,1?S)-4-methyl-3-triphenyl-pnosphonium-1-[1?-methyl(methyiphenyl)]-2-hydrido-2-borazetidinium bromide?the first example of a four-membered C?B?N?C heterocycle, J. Chem. Soc., Chem. Commun., issue.2, pp.287-289, 1995.

V. Chapitre, Synthèse des résultats de classification pour la nitrocellulose industrielle aux fins de la distribution et de l'utilisation conformément au chapitre 2.17 du SGH, qui peuvent être appliquées aux produits à base de nitrocellulose industrielle, Synthèse d'aminoboranes atropoisomères -Etude de la chiralité axiale C-B 208 Schéma 135 : Conditions de borylations appliquées, 2019.

D. , E. , and H. , Le complexe TMP 220B a conduit un tert-butyle au sein de l'amine-borane 220H a conduit à un rendement comparable (225, 86%) alors que l'utilisation d'un cyclohexane 220E a fait chuter le rendement isolé (226, 49%), La borylation des deux substrats de départ a conduit à des composés atropoisomères à température ambiante dans le cas des complexes amine-boranes 220B

, Utilisation des commandes de syntaxe, L'analyse des données de sondage avec SPSS, pp.105-110, 2018.

, Les nouveaux États membres de l'UE sont des concurrents plus redoutables que la Chine, 2008.

M. Lavoie, Chapitre 6. La réception de La Création du monde : un mélange des genres, Musique et modernité en France, pp.171-192

. Pd, Graphique 10. Frais administratifs pour obtenir un visa ou permis de travail, 2014

, Est-ce que le stade 0 de GOLD prédit le développement de la BPCO ?, Revue des Maladies Respiratoires, vol.23, issue.1, pp.16-17, 2006.

F. Hugot and É. Abgrall, Étude statistique de la fissuration des revêtements et modélisation du comportement mécanique de films déposés sur des substrats Inox 316L, Mécanique & Industries, vol.9, issue.3, pp.177-182, 2008.

W. Rundel, Synthese von 2,4,6-Tri-tert-butyl-[1-13C]anilin und 2,4,6-Tri-tert-butyl-[1-13C]brombenzol, Chemische Berichte, vol.111, issue.10, pp.3510-3513, 1978.

D. Le-bromure, DIPAB pour conduire au produit 232 attendu avec un rendement de 92% (Schéma 137). Cependant, le produit 232 ne possède pas de chiralité axiale à 25°C

F. Gallais, J. Labarre, and P. De-loth, Évolution de la rotation magnétique (effet Faraday) de la liaison (C ? E) et de quelques liaisons (E ? E) en fonction de la position de l?élément E dans la classification périodique: les facteurs de la rotation de liaison, Journal de Chimie Physique, vol.64, pp.247-252, 1967.

B. Lapinalie, ??Alors, qu?est-ce qui nous lie ? celui avec qui nous nous embarquons?????, Champ lacanien, vol.N?16, issue.1, p.61, 2015.

L. Fleury, 8. Le public populaire : une catégorie réalisée, Le TNP de Vilar, vol.86, pp.183-201
URL : https://hal.archives-ouvertes.fr/hal-02385117

, Intramolecular Interactions between Chalcogen Atoms: Organoseleniums Derived from 1-Bromo-4-tert-butyl-2, 6- di(formyl)benzene, Schéma, vol.138

, Graphique 1.22. Part des sous-indicateurs selon le nombre de pays qui les utilise

Z. Wu, D. Ma, B. Zhou, X. Ji, X. Ma et al., Palladium-Catalyzed Alkylation with Alkyl Halides by C(sp3)?H Activation, Angewandte Chemie International Edition, vol.56, issue.40, pp.12288-12291, 2017.

V. R. Bhonde, B. T. O'neill, and S. L. Buchwald, An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles, Angewandte Chemie International Edition, vol.55, issue.5, pp.1849-1853, 2015.

V. Chapitre, Chapitre XII. Essai De Synthèse, Le pouvoir et les groupes de pression, pp.266-280, 1971.

A. Staubitz, A. P. Robertson, and I. Manners, Ammonia-Borane and Related Compounds as Dihydrogen Sources, Chemical Reviews, vol.110, issue.7, pp.4079-4124, 2010.

. Revue-sur-le-nitrure-de-bore, . T. Ses-dérivés-:-r, C. K. Paine, and . Narula, Chem. Rev, vol.90, pp.73-91, 1990.

L. Pasumansky, C. T. Goralski, and B. Singaram, Lithium Aminoborohydrides: Powerful, Selective, Air-Stable Reducing Agents, Organic Process Research & Development, vol.10, issue.5, pp.959-970, 2006.

J. V. Kanth, Borane?Amine Complexes for Hydroboration, ChemInform, vol.34, issue.33, pp.57-66, 2003.

H. Nmr, Figure 4?figure supplement 1. NMR spectrometry of synthesized G-1., MHz, vol.6, issue.300

, Synergistic Effect of EtOAc/H2O Biphasic Solvent and Ru/C Catalyst for Cornstalk Hydrolysis Residue Depolymerization, Rf (EtOAc:Pet. Ether

H. Kameo, S. Ishii, and H. Nakazawa, Facile synthesis of rhodium and iridium complexes bearing a [PEP]-type ligand (E = Ge or Sn) via E?C bond cleavage, Dalton Transactions, vol.41, issue.37, p.11386, 2012.

M. M. Mojtahedi, N. N. , and H. Veisi, Experimental part 2-B-((N-tert-butyl-N-isopropylamino)-2-methylnaphth-1-yl)-borane ou 2-methyl_N-isopropyl,N-tert-butyl_atropo 225 was obtained from 1-bromo-2-methylnaphthalene, Org. Chem. Lett, vol.10, pp.121-125, 2013.

?. Nh(i-pr,

. Mol and . Wt, Table 1: Binding free energies of Cpd-5 in WT and mutant systems (kcal/mol)., pp.267-289

M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb et al., Gaussian 16, Revision A.03, 2016.

R. Ditchfield, ;. Cheeseman, G. Trucks, T. A. Keith, and M. J. Frisch, J. Chem. Phys, vol.104, p.5497, 1974.

M. W. Lodewyk, M. R. Siebert, and D. J. Tantillo, Computational Prediction of1H and13C Chemical Shifts: A Useful Tool for Natural Product, Mechanistic, and Synthetic Organic Chemistry, Chemical Reviews, vol.112, issue.3, pp.1839-1862, 2011.