G. References and .. , 86 III. Synthesis and self-assembly properties of new bis-urea monomers, p.89

A. Introduction and .. , 176 B. Design rules and choice of the catalytic reaction, p.177

G. Experimental and :. , 193 1. Supplementary Figures

H. References and .. , 203 VI. Gold(I) complexes supported on supramolecular scaffolds: characterisation and use in catalysis, p.205

(. Gold, Emerging strategies to control the selectivity of gold catalysis, p.208

B. Synthesis and B. , 212 1. Synthesis and characterisation, p.212

S. R. Gilbertson, S. E. Collibee, and A. Agarkov, Asymmetric Catalysis with Libraries of Palladium ??-Turn Phosphine Complexes, Journal of the American Chemical Society, vol.122, issue.27, pp.6522-6523, 2000.
DOI : 10.1021/ja992306f

A. Agarkov, S. Greenfield, D. Xie, R. Pawlick, G. Starkey et al., Synthesis of phosphine containing amino acids: Utilization of peptide synthesis in ligand design, Biopolymers, vol.121, issue.1, pp.48-73, 2006.
DOI : 10.1002/bip.20395

R. Sambasivan and Z. T. Ball, Metallopeptides for Asymmetric Dirhodium Catalysis, Journal of the American Chemical Society, vol.132, issue.27, pp.9289-9291, 2010.
DOI : 10.1021/ja103747h

L. Zheng, A. Marcozzi, J. Y. Gerasimov, and A. Herrmann, Conformationally Constrained Cyclic Peptides: Powerful Scaffolds for Asymmetric Catalysis, Angewandte Chemie International Edition, vol.9, issue.29, pp.7599-7603, 2014.
DOI : 10.1002/anie.201403829

S. Dey and A. Jäschke, Tuning the Stereoselectivity of a DNA-Catalyzed Michael Addition through Covalent Modification, Angewandte Chemie International Edition, vol.4, issue.38, pp.11279-11282, 2015.
DOI : 10.1002/anie.201503838

S. Roe, D. J. Ritson, T. Garner, M. Searle, and J. E. Moses, Tuneable DNA-based asymmetric catalysis using a G-quadruplex supramolecular assembly, Chemical Communications, vol.9, issue.24, pp.4309-4311, 2010.
DOI : 10.1039/c0cc00194e

T. R. Ward, Artificial Metalloenzymes Based on the Biotin???Avidin Technology: Enantioselective Catalysis and Beyond, Accounts of Chemical Research, vol.44, issue.1, pp.47-57, 2011.
DOI : 10.1021/ar100099u

A. J. Boersma, J. E. Klijn, B. L. Feringa, and G. Roelfes, DNA-Based Asymmetric Catalysis: Sequence-Dependent Rate Acceleration and Enantioselectivity, Journal of the American Chemical Society, vol.130, issue.35, pp.11783-11790, 2008.
DOI : 10.1021/ja803170m

E. Largy, A. Marchand, S. Amrane, V. Gabelica, and J. Mergny, Quadruplex Turncoats: Cation-Dependent Folding and Stability of Quadruplex-DNA Double Switches, Journal of the American Chemical Society, vol.138, issue.8, pp.2780-2792, 2016.
DOI : 10.1021/jacs.5b13130
URL : https://hal.archives-ouvertes.fr/hal-01524154

C. Wang, G. Jia, J. Zhou, Y. Li, Y. Liu et al., Enantioselective Diels-Alder Reactions with G-Quadruplex DNA-Based Catalysts, Angewandte Chemie International Edition, vol.17, issue.37, pp.9352-9355, 2012.
DOI : 10.1002/anie.201204850

C. Wang, Y. Li, G. Jia, Y. Liu, S. Lu et al., Enantioselective Friedel???Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme, Chemical Communications, vol.17, issue.50, pp.6232-6234, 2012.
DOI : 10.1039/c2cc31320k

Y. Nagata, T. Nishikawa, and M. Suginome, )-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main-Chain Helical Chirality, Journal of the American Chemical Society, vol.136, issue.45, pp.15901-15904, 2014.
DOI : 10.1021/ja509531t

Y. Nagata, T. Nishikawa, and M. Suginome, Exerting Control over the Helical Chirality in the Main Chain of Sergeants-and-Soldiers-Type Poly(quinoxaline-2,3-diyl)s by Changing from Random to Block Copolymerization Protocols, Journal of the American Chemical Society, vol.137, issue.12, pp.4070-4073, 2015.
DOI : 10.1021/jacs.5b01422

T. Sato, K. Terao, A. Teramoto, and M. Fujiki, On the Composition-Driven Helical Screw-Sense Inversion of Chiral???Achiral Random Copolymers, Macromolecules, vol.35, issue.14, pp.5355-5357, 2002.
DOI : 10.1021/ma020426t

Y. Ke, Y. Nagata, T. Yamada, and M. Suginome, Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis, Angewandte Chemie International Edition, vol.132, issue.32, pp.9333-9337, 2015.
DOI : 10.1002/anie.201502209

J. J. Van-gorp, J. A. Vekemans, and E. W. Meijer, -Symmetrical Supramolecular Architectures:?? Fibers and Organic Gels from Discotic Trisamides and Trisureas, Journal of the American Chemical Society, vol.124, issue.49, pp.14759-14769, 2002.
DOI : 10.1021/ja020984n
URL : https://hal.archives-ouvertes.fr/hal-00675322

J. Van-gestel, A. R. Palmans, B. Titulaer, J. A. Vekemans, and E. W. Meijer, -Symmetrical Molecules, Journal of the American Chemical Society, vol.127, issue.15, pp.5490-5494, 2005.
DOI : 10.1021/ja0501666
URL : https://hal.archives-ouvertes.fr/in2p3-00850157

S. Cantekin, T. F. De-greef, and A. R. Palmans, Benzene-1,3,5-tricarboxamide: a versatile ordering moiety for supramolecular chemistry, Chemical Society Reviews, vol.38, issue.12, pp.6125-6137, 2012.
DOI : 10.1039/c2cs35156k

P. J. Stals, J. C. Everts, R. De-bruijn, I. A. Filot, M. M. Smulders et al., Dynamic Supramolecular Polymers Based on Benzene-1,3,5-tricarboxamides: The Influence of Amide Connectivity on Aggregate Stability and Amplification of Chirality, Chemistry - A European Journal, vol.13, issue.3, pp.810-821, 2010.
DOI : 10.1002/chem.200902635

P. J. Stals, J. F. Haveman, R. Martín-rapún, C. F. Fitié, A. R. Palmans et al., The influence of oligo(ethylene glycol) side chains on the self-assembly of benzene-1,3,5-tricarboxamides in the solid state and in solution, J. Mater. Chem., vol.111, issue.1, pp.124-130, 2009.
DOI : 10.1039/B816418E

T. Metzroth, A. Hoffmann, R. Martín-rapún, M. M. Smulders, K. Pieterse et al., -discotics as determined by X-ray diffraction, quantum-chemical calculations, Fast-MAS NMR and CD spectroscopy, Chem. Sci., vol.122, issue.1, pp.69-76, 2011.
DOI : 10.1039/C0SC00292E

M. Kristiansen, P. Smith, C. Chanzy, V. Baerlocher, L. Gramlich et al., Structural Aspects of 1,3,5-Benzenetrisamides???A New Family of Nucleating Agents, Crystal Growth & Design, vol.9, issue.6, pp.2556-2558, 2009.
DOI : 10.1021/cg900139d
URL : https://hal.archives-ouvertes.fr/hal-00413877

L. Brunsveld, A. P. Schenning, M. A. Broeren, H. M. Janssen, J. A. Vekemans et al., )-3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide in Dilute Solution, Chemistry Letters, vol.29, issue.3, pp.292-293, 2000.
DOI : 10.1246/cl.2000.292

M. M. Smulders, I. A. Filot, J. M. Leenders, P. Van-der-schoot, A. R. Palmans et al., Tuning the Extent of Chiral Amplification by Temperature in a Dynamic Supramolecular Polymer, Journal of the American Chemical Society, vol.132, issue.2, pp.611-619, 2010.
DOI : 10.1021/ja908053d

M. M. Smulders, P. J. Stals, T. Mes, T. F. Paffen, A. P. Schenning et al., Probing the Limits of the Majority-Rules Principle in a Dynamic Supramolecular Polymer, Journal of the American Chemical Society, vol.132, issue.2, pp.620-626, 2010.
DOI : 10.1021/ja9080875

A. Desmarchelier, M. Raynal, P. Brocorens, N. Vanthuyne, and L. Bouteiller, Revisiting the assembly of amino ester-based benzene-1,3,5-tricarboxamides: chiral rods in solution, Chem. Commun., vol.116, issue.34, pp.7397-7400, 2015.
DOI : 10.1039/C5CC01513H
URL : https://hal.archives-ouvertes.fr/hal-01141988

M. A. Veld, D. Haveman, A. R. Palmans, and E. W. Meijer, Sterically demanding benzene-1,3,5-tricarboxamides: tuning the mechanisms of supramolecular polymerization and chiral amplification, Soft Matter, vol.36, issue.2, pp.524-531, 2011.
DOI : 10.1021/jp1072928

M. De-loos, J. H. Van-esch, R. M. Kellogg, and B. L. Feringa, C3-Symmetric, amino acid based organogelators and thickeners: a systematic study of structure???property relations, Tetrahedron, vol.63, issue.31, pp.7285-7301, 2007.
DOI : 10.1016/j.tet.2007.02.066

A. Desmarchelier, B. G. Alvarenga, X. Caumes, L. Dubreucq, C. Troufflard et al., Tuning the nature and stability of self-assemblies formed by ester benzene 1,3,5-tricarboxamides: the crucial role played by the substituents, Soft Matter, vol.9, issue.37, pp.7824-7838, 2016.
DOI : 10.1039/C6SM01601D
URL : https://hal.archives-ouvertes.fr/hal-01362222

J. W. Steed, Anion-tuned supramolecular gels: a natural evolution from urea supramolecular chemistry, Chemical Society Reviews, vol.7, issue.10, pp.3686-3699, 2010.
DOI : 10.1039/c0nj00278j

S. Boileau, L. Bouteiller, F. Lauprêtre, and F. Lortie, Soluble supramolecular polymers based on urea compounds, New Journal of Chemistry, vol.24, issue.11, pp.845-848, 2000.
DOI : 10.1039/b006742n

E. Sabadini, K. R. Francisco, and L. Bouteiller, Bis-Urea-Based Supramolecular Polymer: The First Self-Assembled Drag Reducer for Hydrocarbon Solvents, Langmuir, vol.26, issue.3, pp.1482-1486, 2010.
DOI : 10.1021/la903683e

V. Simic, L. Bouteiller, and M. Jalabert, Highly Cooperative Formation of Bis-Urea Based Supramolecular Polymers, Journal of the American Chemical Society, vol.125, issue.43, pp.13148-13154, 2003.
DOI : 10.1021/ja037589x

L. Bouteiller, O. Colombani, F. Lortie, and P. Terech, Thickness Transition of a Rigid Supramolecular Polymer, Journal of the American Chemical Society, vol.127, issue.24, pp.8893-8898, 2005.
DOI : 10.1021/ja0511016

P. Brocorens, M. Linares, C. Guyard-duhayon, R. Guillot, B. Andrioletti et al., Conformational Plasticity of Hydrogen Bonded Bis-urea Supramolecular Polymers, The Journal of Physical Chemistry B, vol.117, issue.17, pp.5379-5386, 2013.
DOI : 10.1021/jp401915y
URL : https://hal.archives-ouvertes.fr/hal-00993522

T. Pinault, B. Isare, and L. Bouteiller, Solvents with Similar Bulk Properties Induce Distinct Supramolecular Architectures, ChemPhysChem, vol.20, issue.4, pp.816-819, 2006.
DOI : 10.1002/cphc.200500636

T. Shikata, T. Nishida, B. Isare, M. Linares, R. Lazzaroni et al., -Dodecane, The Journal of Physical Chemistry B, vol.112, issue.29, pp.8459-8465, 2008.
DOI : 10.1021/jp800495v
URL : https://hal.archives-ouvertes.fr/hal-01506569

F. Ouhib, M. Raynal, B. Jouvelet, B. Isare, and L. Bouteiller, Hydrogen bonded supramolecular polymers in moderately polar solvents, Chemical Communications, vol.20, issue.38, pp.10683-10685, 2011.
DOI : 10.1039/c1cc14590h

B. Isare, M. Linares, R. Lazzaroni, and L. Bouteiller, Engineering the Cavity of Self-Assembled Dynamic Nanotubes, The Journal of Physical Chemistry B, vol.113, issue.11, pp.3360-3364, 2009.
DOI : 10.1021/jp810236z

I. Giannicchi, B. Jouvelet, B. Isare, M. Linares, A. Dalla-cort et al., Orthohalogen substituents dramatically enhance hydrogen bonding of aromatic ureas in solution, Chem. Commun., vol.20, issue.5, pp.611-613, 2014.
DOI : 10.1039/C3CC47447J
URL : https://hal.archives-ouvertes.fr/hal-01122545

B. Isare, M. Linares, L. Zargarian, S. Fermandjian, M. Miura et al., Chirality in Dynamic Supramolecular Nanotubes Induced by a Chiral Solvent, Chemistry - A European Journal, vol.38, issue.1, pp.173-177, 2010.
DOI : 10.1002/chem.200902399

P. Pyykkö, Theoretical Chemistry of Gold, Angewandte Chemie International Edition, vol.43, issue.34, pp.4412-4456, 2004.
DOI : 10.1002/anie.200300624

J. Dubarle-offner, J. Moussa, H. Amouri, B. Jouvelet, L. Bouteiller et al., Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies, Chemistry - A European Journal, vol.135, issue.12, pp.3985-3990, 2016.
DOI : 10.1002/chem.201504441
URL : https://hal.archives-ouvertes.fr/hal-01318173

E. Huerta, B. Van-genabeek, B. A. Lamers, M. M. Koenigs, and E. W. Meijer, Triggering Activity of Catalytic Rod-Like Supramolecular Polymers, Chemistry - A European Journal, vol.481, issue.9, pp.3682-3690, 2015.
DOI : 10.1002/chem.201405410

L. N. Neumann, M. B. Baker, C. M. Leenders, I. K. Voets, R. P. Lafleur et al., Supramolecular polymers for organocatalysis in water, Org. Biomol. Chem., vol.63, issue.28, pp.7711-7719, 2015.
DOI : 10.1039/C5OB00937E

M. De-torres, R. Van-hameren, R. J. Nolte, A. E. Rowan, and J. A. Elemans, Photocatalytic oxidation of stilbene by self-assembled stacks of manganese porphyrins, Chemical Communications, vol.6, issue.92, pp.10787-10789, 2013.
DOI : 10.1039/c3cc45608k

M. Raynal, F. Portier, P. W. Van-leeuwen, and L. Bouteiller, Tunable Asymmetric Catalysis through Ligand Stacking in Chiral Rigid Rods, Journal of the American Chemical Society, vol.135, issue.47, pp.17687-17690, 2013.
DOI : 10.1021/ja408860s

T. Yang, A. Ferrali, F. Sladojevich, L. Campbell, and D. J. Dixon, Br??nsted Base/Lewis Acid Cooperative Catalysis in the Enantioselective Conia-Ene Reaction, Journal of the American Chemical Society, vol.131, issue.26, pp.9140-9141, 2009.
DOI : 10.1021/ja9004859

S. J. Connon, Organocatalysis Mediated by (Thio)urea Derivatives, Chemistry - A European Journal, vol.7, issue.21, pp.5418-5427, 2006.
DOI : 10.1002/chem.200501076

P. A. Duckmanton, A. J. Blake, and J. B. Love, Palladium and Rhodium Ureaphosphine Complexes:?? Exploring Structural and Catalytic Consequences of Anion Binding, Inorganic Chemistry, vol.44, issue.22, pp.7708-7710, 2005.
DOI : 10.1021/ic051110f

L. K. Knight, Z. Freixa, P. W. Van-leeuwen, and J. N. Reek, -Coordinating Phosphine Ligands, Organometallics, vol.25, issue.4, pp.954-960, 2006.
DOI : 10.1021/om050865r
URL : https://hal.archives-ouvertes.fr/inria-00424854

J. Meeuwissen, A. J. Sandee, B. De-bruin, M. A. Siegler, A. L. Spek et al., Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde, Organometallics, vol.29, issue.11, pp.2413-2421, 2010.
DOI : 10.1021/om901028z

J. Meeuwissen, M. Kuil, A. M. Van-der-burg, A. J. Sandee, and J. N. Reek, Application of a Supramolecular-Ligand Library for the Automated Search for Catalysts for the Asymmetric Hydrogenation of Industrially Relevant Substrates, Chemistry - A European Journal, vol.66, issue.39, pp.10272-10279, 2009.
DOI : 10.1002/chem.200901110

X. Wang, A. Thevenon, J. L. Brosmer, I. Yu, S. I. Khan et al., -Lactide and ??-Caprolactone, Journal of the American Chemical Society, vol.136, issue.32, pp.11264-11267, 2014.
DOI : 10.1021/ja505883u
URL : https://hal.archives-ouvertes.fr/hal-00787126

]. V. Simic, L. Bouteiller, M. Jalabert, J. Am, B. Isare et al., Highly Cooperative Formation of Bis-Urea Based Supramolecular Polymers, Journal of the American Chemical Society, vol.125, issue.43, pp.13148-13154, 2003.
DOI : 10.1021/ja037589x

J. T. Manka, F. Guo, J. Huang, H. Yin, J. M. Farrar et al., Synthesis of Polyfunctionalized Biphenyls as Intermediates for a New Class of Liquid Crystals, The Journal of Organic Chemistry, vol.68, issue.25, pp.9574-9588, 2003.
DOI : 10.1021/jo030212p

D. Rivillo, H. Gulyás, J. Benet-buchholz, E. C. Escudero-adán, Z. Freixa et al., Catalysis by Design: Wide-Bite-Angle Diphosphines by Assembly of Ditopic Ligands for Selective Rhodium-Catalyzed Hydroformylation, Angewandte Chemie International Edition, vol.25, issue.38, pp.7247-7250, 2007.
DOI : 10.1002/anie.200701255

N. Soh, T. Ariyoshi, T. Fukaminato, H. Nakajima, K. Nakano et al., Swallow-tailed perylene derivative: a new tool for fluorescent imaging of lipid hydroperoxides, Organic & Biomolecular Chemistry, vol.522, issue.23, pp.3762-3768, 2007.
DOI : 10.1039/b713223a

A. I. Meyers, G. S. Poindexter, and Z. Brich, Asymmetric synthesis of (+)- or (-)-2-methyloctanal via the metalloenamines of chiral alkoxy amines, The Journal of Organic Chemistry, vol.43, issue.5, pp.892-898, 1978.
DOI : 10.1021/jo00399a021

M. J. Mckennon, A. I. Meyers, K. Drauz, and M. Schwarm, A convenient reduction of amino acids and their derivatives, The Journal of Organic Chemistry, vol.58, issue.13, pp.3568-3571, 1993.
DOI : 10.1021/jo00065a020

C. A. Cariou, B. M. Kariuki, and J. S. Snaith, Stereoselective synthesis of 2,4,5-trisubstituted piperidines by carbonyl ene and Prins cyclisations, Organic & Biomolecular Chemistry, vol.45, issue.18, pp.3337-3348, 2008.
DOI : 10.1039/b808644c

M. Roman, C. Cannizzo, T. Pinault, B. Isare, B. Andrioletti et al., Supramolecular Balance: Using Cooperativity To Amplify Weak Interactions, Journal of the American Chemical Society, vol.132, issue.47, pp.16818-16824, 2010.
DOI : 10.1021/ja105717u
URL : https://hal.archives-ouvertes.fr/hal-00695897

. Hz, 13 C{ 1 H} NMR (75 MHz, Acetone-d6) ? 173.1, 167.0 166, p.85

B. Val, Obtained from (S)-valine using General Method A, then B, with an overall yield of 56%, as an offwhite gum

. Racemate, Catalytic reaction, p.84

J. S. Siegel, P. Chirality-cintas, J. E. Hein, and D. G. Blackmond, (b) Bailey, J. Origins Life Evol, Acc. Chem. Res, vol.10, issue.45, pp.24-27, 1998.

R. Noyori, M. Kitamura, K. Soai, T. Shibata, H. Morioka et al., Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication, and Amplification, Angewandte Chemie International Edition in English, vol.30, issue.1, pp.49-69, 1991.
DOI : 10.1002/anie.199100491

E. Yashima, T. Matsushima, Y. Okamoto, E. Yashima, and Y. Okamoto, Poly((4-carboxyphenyl)acetylene) as a Probe for Chirality Assignment of Amines by Circular Dichroism, Journal of the American Chemical Society, vol.117, issue.46, pp.11596-11597, 1995.
DOI : 10.1021/ja00151a032

F. Aparicio, E. Matesanz, and L. Sanchez, Cooperative self-assembly of linear organogelators. Amplification of chirality and crystal growth of pharmaceutical ingredients, Chemical Communications, vol.33, issue.46, pp.5757-5759, 2012.
DOI : 10.1039/c2cc31818k

R. Eelkema and B. L. Feringa, Amplification of chirality in liquid crystals, Organic & Biomolecular Chemistry, vol.121, issue.136, pp.3729-3745, 2006.
DOI : 10.1002/asia.200600116

A. E. Rowan and R. J. Nolte, Helical Molecular Programming, Angewandte Chemie International Edition, vol.37, issue.1-2, pp.63-68, 1998.
DOI : 10.1002/(SICI)1521-3773(19980202)37:1/2<63::AID-ANIE63>3.0.CO;2-4

. Chem, M. M. Soc-green, B. A. Garetz, B. Munoz, H. P. Chang et al., (b) van Gestel, J. Am. Chem. Soc. Cook, R.; Lifson, S. Science J.; van der Schoot, P J. Macromolecules Gestel, J. Macromolecules J.; van der Schoot, P J. J. Chem. Phys, vol.111, issue.120, pp.6452-6454, 1989.

H. M. Eikelder, A. J. Markvoort, T. F. De-greef, P. A. Hilbers, S. Jabbari-farouji et al., An Equilibrium Model for Chiral Amplification in Supramolecular Polymers, The Journal of Physical Chemistry B, vol.116, issue.17, pp.5291-5301, 2012.
DOI : 10.1021/jp300622m

J. W. Faller, A. R. Lavoie, J. Parr, K. Mikami, M. Yamanaka et al., Chiral Poisoning and Asymmetric Activation, Chemical Reviews, vol.103, issue.8, pp.3345-3367, 2003.
DOI : 10.1021/cr0200318

M. M. Smulders, A. P. Schenning, E. W. Meijer, and I. A. Filot, -Symmetrical Discotic Triamides, For the chirality amplification properties of alkyl BTAs see, pp.606-611, 2008.
DOI : 10.1021/ja075987k
URL : https://hal.archives-ouvertes.fr/jpa-00254934

M. M. Smulders, P. Stals, and T. Pfaffen, Tuning the Extent of Chiral Amplification by Temperature in a Dynamic Supramolecular Polymer, Journal of the American Chemical Society, vol.132, issue.2, pp.611-619, 2010.
DOI : 10.1021/ja908053d

H. Fernandez-perez, S. M. Donald, I. J. Munslow, J. Benet-buchholz, and F. Maseras, Highly Modular P???OP Ligands for Asymmetric Hydrogenation: Synthesis, Catalytic Activity, and Mechanism, Chemistry - A European Journal, vol.14, issue.22, pp.6495-6508, 2010.
DOI : 10.1002/chem.200902915

Y. See:-nagata, T. Nishikawa, and M. Suginome, )-3-Octyloxymethyl Side Chains as an Efficient Amplifier of Alkane Solvent Effect Leading to Switch of Main-Chain Helical Chirality, Journal of the American Chemical Society, vol.136, issue.45, pp.15901-15904, 2014.
DOI : 10.1021/ja509531t

P. Jana, A. Paikar, S. Bera, S. K. Maity, and D. Haldar, Porous Organic Material from Discotic Tricarboxyamide: Side Chain???Core interactions, Organic Letters, vol.16, issue.1, pp.38-41, 2014.
DOI : 10.1021/ol402865t

J. Roosma, T. Mes, P. Leclère, A. R. Palmans, and E. W. Meijer, Supramolecular Materials from Benzene-1,3,5-tricarboxamide-Based Nanorods, Journal of the American Chemical Society, vol.130, issue.4, pp.1120-1121, 2008.
DOI : 10.1021/ja0774764

S. I. Kirin, H. B. Kraatz, and N. Metzler-nolte, Chirality transfer from stacked aromatic rings to prochiral metals is known for disubstituted ferrocene peptides 35a and has been postulated for supramolecular catalysts. 22k,35b-f For one example of chirality transfer in covalent asymmetric catalysts see reference 35g, The relative Re or Si, pp.348-354, 2006.

A. J. Bissette and S. P. Fletcher, Mechanisms of Autocatalysis, Angewandte Chemie International Edition, vol.75, issue.49, pp.12800-12826, 2013.
DOI : 10.1002/anie.201303822

Y. Sohtome, S. Tanaka, K. Takada, T. Yamaguchi, and K. Nagasawa, Solvent-Dependent Enantiodivergent Mannich-Type Reaction: Utilizing a Conformationally Flexible Guanidine/Bisthiourea Organocatalyst, Angewandte Chemie International Edition, vol.670, issue.48, pp.9254-9257, 2010.
DOI : 10.1002/anie.201005109

T. Yamada, Y. Nagata, and M. Suginome, Non-hydrogen-bonding-based, solvent-dependent helix inversion between pure P-helix and pure M-helix in poly(quinoxaline-2,3-diyl)s bearing chiral side chains, Chemical Communications, vol.111, issue.27, p.4914, 2010.
DOI : 10.1039/c001564d

B. A. Le-bailly, L. Byrne, and J. Clayden, Refoldable Foldamers: Global Conformational Switching by Deletion or Insertion of a Single Hydrogen Bond, Angewandte Chemie International Edition, vol.84, issue.6, pp.2132-2136, 2016.
DOI : 10.1351/PAC-CON-11-08-23

J. Wang and B. L. Feringa, Dynamic Control of Chiral Space in a Catalytic Asymmetric Reaction Using a Molecular Motor, Science, vol.103, issue.6, pp.1429-1432, 2011.
DOI : 10.1021/jo902634a

X. Tian, C. Cassani, Y. Liu, A. Moran, A. Urakawa et al., Diastereodivergent Asymmetric Sulfa-Michael Additions of ??-Branched Enones using a Single Chiral Organic Catalyst, Journal of the American Chemical Society, vol.133, issue.44, pp.17934-17941, 2011.
DOI : 10.1021/ja207847p

A. R. Palmans and E. W. Meijer, Amplification of Chirality in Dynamic Supramolecular Aggregates, Angewandte Chemie International Edition, vol.125, issue.47, pp.8948-8968, 2007.
DOI : 10.1002/anie.200701285

E. Yashima, K. Maeda, H. Iida, Y. Furusho, and K. Nagai, Helical Polymers: Synthesis, Structures, and Functions, Chemical Reviews, vol.109, issue.11, pp.6102-6211, 2009.
DOI : 10.1021/cr900162q

M. Liu, L. Zhang, and T. Wang, Supramolecular Chirality in Self-Assembled Systems, Chemical Reviews, vol.115, issue.15, pp.7304-7397, 2015.
DOI : 10.1021/cr500671p

M. Sawamura, R. Kuwano, and Y. Ito, trans-Chelating Chiral Diphosphane Ligands Bearing FlexibleP-Alkyl Substituents (AlkylTRAPs) and their Application to the Rhodium-Catalyzed Asymmetric Hydrosilylation of Simple Ketones, Angewandte Chemie International Edition in English, vol.4, issue.1, pp.111-113, 1994.
DOI : 10.1002/anie.199401111

C. Reyes, A. Prock, and W. P. Giering, )-BINAP, Organometallics, vol.21, issue.3, pp.546-554, 2002.
DOI : 10.1021/om0106682

C. Reyes, A. Prock, and W. P. Giering, Analysis of the enantioselectivities and initial rates of the hydrosilylation of acetophenone catalyzed by [Rh(cod)Cl]2/(chiral diphosphine). The quantitative analysis of ligand effects, Journal of Organometallic Chemistry, vol.671, issue.1-2, pp.13-26, 2003.
DOI : 10.1016/S0022-328X(02)02221-0

N. S. Shaikh, S. Enthaler, K. Junge, and M. Beller, Iron-Catalyzed Enantioselective Hydrosilylation of Ketones, Angewandte Chemie International Edition, vol.102, issue.13, pp.2497-2501, 2008.
DOI : 10.1002/anie.200705624

H. Brunner and W. Miehling, Asymmetrische katalysen, Journal of Organometallic Chemistry, vol.275, issue.2, pp.17-21, 1984.
DOI : 10.1016/0022-328X(84)85066-4

B. H. Lipshutz, K. Noson, and W. Chrisman, Ligand-Accelerated, Copper-Catalyzed Asymmetric Hydrosilylations of Aryl Ketones, Journal of the American Chemical Society, vol.123, issue.51, pp.12917-12918, 2001.
DOI : 10.1021/ja011529e

S. Sirol, J. Courmarcel, N. Mostefai, and O. Riant, Efficient Enantioselective Hydrosilylation of Ketones Catalyzed by Air Stable Copper Fluoride???Phosphine Complexes, Organic Letters, vol.3, issue.25, pp.4111-4113, 2001.
DOI : 10.1021/ol0169170

B. H. Lipshutz, K. Noson, W. Chrisman, and A. Lower, phosphine Ligands, Journal of the American Chemical Society, vol.125, issue.29, pp.8779-8789, 2003.
DOI : 10.1021/ja021391f

B. H. Lipshutz and B. A. Frieman, CuH in a Bottle: A Convenient Reagent for Asymmetric Hydrosilylations, Angewandte Chemie International Edition, vol.285, issue.39, pp.6345-6348, 2005.
DOI : 10.1002/anie.200500800

G. Uray, W. Stampfer, and W. M. Fabian, Comparison of Chirasil-DEX CB as gas chromatographic and ULMO as liquid chromatographic chiral stationary phase for enantioseparation of aryl- and heteroarylcarbinols, Journal of Chromatography A, vol.992, issue.1-2, pp.151-157, 2003.
DOI : 10.1016/S0021-9673(03)00274-7

A. Desmarchelier, X. Caumes, M. Raynal, A. Vidal-ferran, P. W. Van-leeuwen et al., Correlation between the Selectivity and the Structure of an Asymmetric Catalyst Built on a Chirally Amplified Supramolecular Helical Scaffold, Journal of the American Chemical Society, vol.138, issue.14, pp.4908-4916, 2016.
DOI : 10.1021/jacs.6b01306

G. V. Goeden, J. C. Huffman, and K. G. Caulton, A copper-(.mu.2-hydrogen) bond can be stronger than an intramolecular phosphorus .fwdarw. copper bond. Synthesis and structure of di-.mu.-hydridobis[.eta.2-1,1,1-tris(diphenylphosphinomethyl)ethane]dicopper, Inorganic Chemistry, vol.25, issue.15, pp.2484-2485, 1986.
DOI : 10.1021/ic00235a002

J. W. Diesveld, E. M. Menger, H. T. Edzes, and W. S. Veeman, High-resolution solid-state phosphorus-31 nuclear magnetic resonance of some triphenylphosphine transition-metal complexes, Journal of the American Chemical Society, vol.102, issue.27, pp.7935-7936, 1980.
DOI : 10.1021/ja00547a021

Y. Li, S. Yu, X. Wu, J. Xiao, W. Shen et al., Iron Catalyzed Asymmetric Hydrogenation of Ketones, Journal of the American Chemical Society, vol.136, issue.10, pp.4031-4040, 2014.
DOI : 10.1021/ja5003636

1. Hz, 18 (m, 1H) 13 C{ 1 H} NMR (101 MHz, CDCl 3 ): ? 134, pp.61-68

I. Atr, HRMS: Calculated for C 25 H 20 NOPAuClNa, pp.3676-636, 1028.

1. Hz, 1.15 (d, J = 6.6 Hz, 6H), 0.88-0.81 (m, 6H). 31 P{ 1 H} NMR (162 MHz, DMSO-d 6 ) ? 33

1. Hz, 12 (m, 9H), 0.87 (m, 6H) 13 C{ 1 H} NMR (75 MHz, DMSO-d 6 ) ? 154, NMR (162 MHz, DMSO-d 6 ) ? 33.3. IR (ATR, pp.69-76, 1238.

J. =. , D. J. Gorin, F. D. Toste, ]. B. Ranieri, I. Escofet et al., 90 (s, 1H), 6.32 (t 13 C{ 1 H} NMR (75 MHz, DMSO-d 6 ): ? 155, NMR (300 MHz 3.03 (q, J = 5.4 Hz, 2H), pp.75-82, 2007.

D. Weber, T. D. Jones, L. L. Adduci, and M. R. Gagné, Strong Electronic and Counterion Effects on Geminal Digold Formation and Reactivity as Revealed by Gold(I)-Aryl Model Complexes, Angewandte Chemie International Edition, vol.2, issue.10, pp.2452-2456, 2012.
DOI : 10.1002/anie.201107659
URL : https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3449216/pdf

P. Pérez-galán, N. Delpont, E. Herrero-gómez, F. Maseras, and A. M. Echavarren, Metal-Arene Interactions in Dialkylbiarylphosphane Complexes of Copper, Silver, and Gold, Chemistry - A European Journal, vol.77, issue.18, pp.5324-5332, 2010.
DOI : 10.1002/chem.200903507

A. Homs, C. Obradors, D. Leboeuf, and A. M. Echavarren, Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions, Advanced Synthesis & Catalysis, vol.10, issue.1, pp.221-228, 2014.
DOI : 10.1002/adsc.201300704
URL : http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4498468

E. Herrero-gómez, C. Nieto-oberhuber, S. López, J. Benet-buchholz, and A. M. Echavarren, Cationic ??1/??2-Gold(I) Complexes of Simple Arenes, Angewandte Chemie International Edition, vol.38, issue.33, pp.5455-5459, 2006.
DOI : 10.1002/anie.200601688

F. Kleinbeck and F. D. Toste, Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols, Journal of the American Chemical Society, vol.131, issue.26, pp.9178-9179, 2009.
DOI : 10.1021/ja904055z
URL : http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2740622

M. Wegener, F. Huber, C. Bolli, C. Jenne, and S. F. Kirsch, as a Weakly Coordinating Anion in Homogeneous Gold Catalysis, Chemistry - A European Journal, vol.63, issue.3, pp.1328-1336, 2015.
DOI : 10.1002/chem.201404487

W. Fang, M. Presset, A. Guérinot, C. Bour, S. Bezzenine-lafollée et al., Silver-Free Two-Component Approach in Gold Catalysis: Activation of [LAuCl] Complexes with Derivatives of Copper, Zinc, Indium, Bismuth, and Other Lewis Acids, Chemistry - A European Journal, vol.16, issue.18, pp.5439-5446, 2014.
DOI : 10.1002/chem.201304831

Y. Wang, A. D. Lackner, and F. D. Toste, Development of Catalysts and Ligands for Enantioselective Gold Catalysis, Accounts of Chemical Research, vol.47, issue.3, pp.889-901, 2014.
DOI : 10.1021/ar400188g

G. L. Hamilton, E. J. Kang, M. Mba, and F. D. Toste, A Powerful Chiral Counterion Strategy for Asymmetric Transition Metal Catalysis, Science, vol.45, issue.10, pp.496-499, 2007.
DOI : 10.1021/ja068819l

L. Rodríguez, T. Roth, J. Fillol, H. Wadepohl, and L. H. Gade, The More Gold-The More Enantioselective: Cyclohydroaminations of ??-Allenyl Sulfonamides with Mono-, Bis-, and Trisphospholane Gold(I) Catalysts, Chemistry - A European Journal, vol.36, issue.12, pp.3721-3728, 2012.
DOI : 10.1002/chem.201103140

K. Yavari, P. Aillard, Y. Zhang, F. Nuter, P. Retailleau et al., Helicenes with Embedded Phosphole Units in Enantioselective Gold Catalysis, Angewandte Chemie International Edition, vol.49, issue.3, pp.861-865, 2014.
DOI : 10.1002/anie.201308377
URL : https://hal.archives-ouvertes.fr/hal-00945885

M. Guitet, P. Zhang, F. Marcelo, C. Tugny, J. Jiménez-barbero et al., NHC-Capped Cyclodextrins (ICyDs): Insulated Metal Complexes, Commutable Multicoordination Sphere, and Cavity-Dependent Catalysis, Angewandte Chemie International Edition, vol.4, issue.28, pp.7213-7218, 2013.
DOI : 10.1002/anie.201301225
URL : https://hal.archives-ouvertes.fr/hal-01397621

A. Ochida, H. Ito, and M. Sawamura, Using Triethynylphosphine Ligands Bearing Bulky End Caps To Create a Holey Catalytic Environment:?? Application to Gold(I)-Catalyzed Alkyne Cyclizations, Journal of the American Chemical Society, vol.128, issue.51, pp.16486-16487, 2006.
DOI : 10.1021/ja066800c

H. Ito, Y. Makida, A. Ochida, H. Ohmiya, and M. Sawamura, Cyclization of Nonterminal Alkynic ??-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand, Organic Letters, vol.10, issue.21, pp.5051-5054, 2008.
DOI : 10.1021/ol802079r

H. Ito, T. Harada, H. Ohmiya, and M. Sawamura, cyclization, Beilstein Journal of Organic Chemistry, vol.7, pp.951-959, 2011.
DOI : 10.3762/bjoc.7.106

M. Galli, J. E. Lewis, and S. M. Goldup, A Stimuli-Responsive Rotaxane-Gold Catalyst: Regulation of Activity and Diastereoselectivity, Angewandte Chemie International Edition, vol.127, issue.46, pp.13545-13549, 2015.
DOI : 10.1002/anie.201505464

Z. Wu, K. Isaac, P. Retailleau, J. Betzer, A. Voituriez et al., Planar Chiral Phosphoramidites with a Paracyclophane Scaffold: Synthesis, Gold(I) Complexes, and Enantioselective Cycloisomerization of Dienynes, Chemistry - A European Journal, vol.13, issue.10, pp.3278-3281, 2016.
DOI : 10.1002/chem.201504658

S. I. Lee, S. M. Kim, M. R. Choi, S. Y. Kim, Y. K. Chung et al., Au(I)-Catalyzed Cyclization of Enynes Bearing an Olefinic Cycle, The Journal of Organic Chemistry, vol.71, issue.25, pp.9366-9372, 2006.
DOI : 10.1021/jo061254r

J. J. Kennedy-smith, S. T. Staben, and F. D. Toste, Gold(I)-Catalyzed Conia-Ene Reaction of ??-Ketoesters with Alkynes, Journal of the American Chemical Society, vol.126, issue.14, pp.4526-4527, 2004.
DOI : 10.1021/ja049487s
URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.502.9747

C. Nieto-oberhuber, M. P. Muñoz, S. López, E. Jiménez-núñez, C. Nevado et al., Gold(I)-Catalyzed Cyclizations of 1,6-Enynes: Alkoxycyclizations andexo/endo Skeletal Rearrangements, Chemistry - A European Journal, vol.30, issue.6, pp.1677-1693, 2006.
DOI : 10.1002/chem.200501088

B. L. Pagenkopf and T. Livinghouse, Photochemical Promotion of the Intramolecular Pauson???Khand Reaction. A New Experimental Protocol for Cobalt-Catalyzed [2 + 2 + 1] Cycloadditions, Journal of the American Chemical Society, vol.118, issue.9, pp.2285-2286, 1996.
DOI : 10.1021/ja9535975

G. Fournet, G. Balme, and J. Gore, Synthese de (e)-arylidene et allylidene cyclopentanes par une annelation catalysee par un complexe de palladium(0), Tetrahedron, vol.47, issue.32, pp.6293-6304, 1991.
DOI : 10.1016/S0040-4020(01)86561-3

M. and ,. Dmso, HRMS: Calculated for C 25 H 30 F 6 N 4 OSNa [M+Na] + : 571.1937, found: 571.1938. 3. Catalytic experiments a) General set-up for the Michael addition reaction In the following, mM) was used as stock solution, p.3328, 1106.

+. Quinine and . Nabarf, For the Michael addition reaction followed by 1 H NMR : With only (rac)-EHUT-ThioPh

C. Lozanova, B. Galabov, M. Ilieva, and G. Vassilev, Infrared intensities and conformation of substituted thioureas, Journal of Molecular Structure, vol.115, pp.427-430, 1984.
DOI : 10.1016/0022-2860(84)80104-0

T. Okino, Y. Hoashi, and Y. Takemoto, Enantioselective Michael Reaction of Malonates to Nitroolefins Catalyzed by Bifunctional Organocatalysts, Journal of the American Chemical Society, vol.125, issue.42, pp.12672-12673, 2003.
DOI : 10.1021/ja036972z

C. M. Mcguirk, J. Mendez-arroyo, A. I. D-'aquino, and C. L. Stern, A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis, Chem. Sci., vol.47, issue.11, pp.6674-6683, 2016.
DOI : 10.1039/C6SC01454B

C. M. Mcguirk, J. Mendez-arroyo, A. M. Lifschitz, and C. A. Mirkin, Allosteric Regulation of Supramolecular Oligomerization and Catalytic Activity via Coordination-Based Control of Competitive Hydrogen-Bonding Events, Journal of the American Chemical Society, vol.136, issue.47, pp.16594-16601, 2014.
DOI : 10.1021/ja508804n

C. M. Mcguirk, C. L. Stern, and C. A. Mirkin, Small Molecule Regulation of Self-Association and Catalytic Activity in a Supramolecular Coordination Complex, Journal of the American Chemical Society, vol.136, issue.12, pp.4689-4696, 2014.
DOI : 10.1021/ja500214r

F. Lortie, S. Boileau, L. Bouteiller, C. Chassenieux, and F. Lauprêtre, Chain Stopper-Assisted Characterization of Supramolecular Polymers, Macromolecules, vol.38, issue.12, pp.5283-5287, 2005.
DOI : 10.1021/ma050168a

T. Pinault, B. Andrioletti, and L. Bouteiller, Chain stopper engineering for hydrogen bonded supramolecular polymers, Beilstein Journal of Organic Chemistry, vol.6, pp.869-875, 2010.
DOI : 10.3762/bjoc.6.102
URL : https://hal.archives-ouvertes.fr/hal-00695894

M. M. Smulders, A. P. Schenning, and E. W. Meijer, -Symmetrical Discotic Triamides, Journal of the American Chemical Society, vol.130, issue.2, pp.606-611, 2008.
DOI : 10.1021/ja075987k
URL : https://hal.archives-ouvertes.fr/jpa-00254934

F. Rodríguez-llansola and E. W. Meijer, Supramolecular Autoregulation, Journal of the American Chemical Society, vol.135, issue.17, pp.6549-6553, 2013.
DOI : 10.1021/ja4006833

N. Srivastava and B. K. Banik, Mayr's Database Of Reactivity Parameters, J. Org. Chem, vol.6823, pp.2109-2114, 2003.

R. P. Herrera, V. Sgarzani, L. Bernardi, and A. Ricci, Catalytic Enantioselective Friedel-Crafts Alkylation of Indoles with Nitroalkenes by Using a Simple Thiourea Organocatalyst, Angewandte Chemie International Edition, vol.116, issue.40, pp.6576-6579, 2005.
DOI : 10.1002/anie.200500227

H. Y. Bae, S. Some, J. S. Oh, Y. S. Lee, and C. E. Song, 9621. developped; (thio)urea [25] , Proline [26] and phosphine [27] derivatives. As we possess a small library of bisurea and BTA ligands and that their association properties are well understood (see Chapter 2 and 3), phosphines-organocatalysed reactions particularly drawn our attention (some of these reactions are listed in the figure below), Chem. Commun, vol.47, 2011.

C. Widauer, H. Grützmacher, and T. Ziegler, Saclay) under the supervision of Arnaud Voituriez and the results are listed below. 2 Catalytics results Figure A6: Substrates tested with our bis-urea and BTA ligands Our chiral bis-urea and BTA ligands (10 mol%) promoted the [3+2] cycloaddition reaction between N-acetyl-3-benzylidene oxindole and benzyl 2,3-butadienenoate with modest yields ( from 40% to 65%, Table A6) The product was racemic in all cases (ee<5%) The bis-urea and BTA ligand solutions were viscous and orange/reddish colour appears upon the addition of the allene which was G. References [1] H. C. Brown, Those reactions (Figure A6) were performed by Maxime Gicquel at the Institut de Chimie des substances naturelles Matsumoto, Y. Lto. [9] J. M. Brown, D. Hulmes, T. P. Layzell, pp.117-138, 1961.

A. Schnyder, L. Hintermann, and A. Togni, Strong Electronic Effects on Enantioselectivity in Rhodium-Catalyzed Hydroborations with Novel Pyrazole-Containing Ferrocenyl Ligands, Angewandte Chemie International Edition in English, vol.34, issue.8, pp.931-933, 1995.
DOI : 10.1002/anie.199509311

S. A. Moteki, D. Wu, K. L. Chandra, D. S. Reddy, and J. M. Takacs, TADDOL-Derived Phosphites and Phosphoramidites for Efficient Rhodium-Catalyzed Asymmetric Hydroboration, Organic Letters, vol.8, issue.14, pp.3097-3100, 2006.
DOI : 10.1021/ol061117g

P. W. Van-leeuwen, Homogeneous Catalysis, 2004.

K. Tamao, N. Ishida, T. Tanaka, and M. Kumada, Silafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanes, Organometallics, vol.2, issue.11, pp.1694-1696, 1983.
DOI : 10.1021/om50005a041

Y. Uozumi and T. Hayashi, Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst, Journal of the American Chemical Society, vol.113, issue.26, pp.9887-9888, 1991.
DOI : 10.1021/ja00026a044

Y. Uozumi, K. Kitayama, and T. Hayashi, Regio- and enantioselective hydrosilylation of 1-arylalkenes by use of palladium-MOP catalyst, Tetrahedron: Asymmetry, vol.4, issue.12, pp.2419-2422, 1993.
DOI : 10.1016/S0957-4166(00)82214-4

T. Hayashi, S. Hirate, K. Kitayama, H. Tsuji, A. Torii et al., Asymmetric Hydrosilylation of Styrenes Catalyzed by Palladium???MOP Complexes:?? Ligand Modification and Mechanistic Studies, The Journal of Organic Chemistry, vol.66, issue.4, pp.1441-1449, 2001.
DOI : 10.1021/jo001614p

J. F. Jensen, B. Y. Svendsen, T. V. La-cour, H. L. Pedersen, and M. Johannsen, Highly Enantioselective Hydrosilylation of Aromatic Alkenes, Journal of the American Chemical Society, vol.124, issue.17, pp.4558-4559, 2002.
DOI : 10.1021/ja025617q

X. Guo, J. Xie, G. Hou, W. Shi, L. Wang et al., Asymmetric palladium-catalyzed hydrosilylation of styrenes using efficient chiral spiro phosphoramidite ligands, Tetrahedron: Asymmetry, vol.15, issue.14, pp.2231-2234, 2004.
DOI : 10.1016/j.tetasy.2004.05.038

K. Junge, B. Wendt, S. Enthaler, and M. Beller, Palladium-Catalyzed Enantioselective Hydrosilylation of Aromatic Olefins, ChemCatChem, vol.43, issue.4, pp.453-458, 2010.
DOI : 10.1002/cctc.200900263

T. Yamamoto, T. Yamada, Y. Nagata, and M. Suginome, High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes, Journal of the American Chemical Society, vol.132, issue.23, pp.7899-7901, 2010.
DOI : 10.1021/ja102428q

Y. Uozumi, H. Tsuji, and T. Hayashi, -Allylstyrene via Hydrosilylation:?? Mechanistic Aspects of Hydrosilylation of Styrenes Catalyzed by Palladium???Phosphine Complexes, The Journal of Organic Chemistry, vol.63, issue.18, pp.6137-6140, 1998.
DOI : 10.1021/jo980100b
URL : https://hal.archives-ouvertes.fr/hal-00735033

S. J. Connon, Organocatalysis Mediated by (Thio)urea Derivatives, Chemistry - A European Journal, vol.7, issue.21, pp.5418-5427, 2006.
DOI : 10.1002/chem.200501076

B. List, Proline-catalyzed asymmetric reactions, Tetrahedron, vol.58, issue.28, pp.5573-5590, 2002.
DOI : 10.1016/S0040-4020(02)00516-1

J. L. Methot and W. R. Roush, Nucleophilic Phosphine Organocatalysis, Advanced Synthesis & Catalysis, vol.346, issue.910, pp.1035-1050, 2004.
DOI : 10.1002/adsc.200404087