MÖSSBAUER PROPERTIES OF SYNTHETIC ANALOGS OF ACTIVE SITES OF THE IRON-SULFUR PROTEINS

R. Frankel , B. Averill , R. Holm

Mössbauer spectroscopy of the synthetic tetramers [Fe4S4(SR)4]2- (R = alkyl, aryl) and the corresponding trianions obtained by one-electron reduction, when compared with available data for 4-Fe and 8-Fe iron-sulfur proteins, shows that these tetramers are electronic analogs of the active sites of the proteins.

Domaines: Articles anciens

R. Frankel, B. Averill, R. Holm. MÖSSBAUER PROPERTIES OF SYNTHETIC ANALOGS OF ACTIVE SITES OF THE IRON-SULFUR PROTEINS. Journal de Physique Colloques, 1974, 35 (C6), pp.C6-107-C6-112. ⟨10.1051/jphyscol:1974609⟩. ⟨jpa-00215709⟩