Behavior of Heptavalent Technetium in Sulfuric Acid under a-Irradiation: Structural Determination of Technetium Sulfate Complexes by X-ray Absorption Spectroscopy and First Principles Calculations

Ibtihel Denden (1) , F. Poineau (2) , M.L. Schlegel (3) , J. Roques (4) , P.-L. Solari (5) , G. Blain (1) , K.R. Czerwinski (2) , R. Essehli (1) , Jacques Barbet (6) , M. Fattahi (1)

1 SUBATECH - Laboratoire SUBATECH Nantes
2 University of Nevada [Reno]
3 LRSI - Laboratoire de Réactivité des Surfaces et des Interfaces
4 IPNO - Institut de Physique Nucléaire d'Orsay
5 SSOLEIL - Synchrotron SOLEIL
6 Cyclotron ARRONAX

Domaines: Radiochimie

Ibtihel Denden, F. Poineau, M.L. Schlegel, J. Roques, P.-L. Solari, et al.. Behavior of Heptavalent Technetium in Sulfuric Acid under a-Irradiation: Structural Determination of Technetium Sulfate Complexes by X-ray Absorption Spectroscopy and First Principles Calculations. Journal of Physical Chemistry A, 2014, pp.1568-1575. ⟨10.1021/jp404967f⟩. ⟨in2p3-01130401⟩