Syntheses of new chiral chimeric photo-organocatalysts

Jiyaun Lyu (1) , Matteo Leone (1) , Aurélie Claraz (1) , Clémence Allain (2) , Luc Neuville (1) , Géraldine Masson (1)

1 ICSN - Institut de Chimie des Substances Naturelles
2 PPSM - Photophysique et Photochimie Supramoléculaires et Macromoléculaires

A new family of chiral chimeric photo-organocatalysts derived from phosphoric acid were synthesized and their spectroscopic and electrochemical properties were investigated. Then, the ability of these photoactivable molecules to catalyse an asymmetric tandem electrophilic b-amination of enecarbamates was evaluated.

Domaines: Chimie organique; Catalyse

Jiyaun Lyu, Matteo Leone, Aurélie Claraz, Clémence Allain, Luc Neuville, et al.. Syntheses of new chiral chimeric photo-organocatalysts. RSC Advances, 2021, 11 (58), pp.36663 - 36669. ⟨10.1039/d1ra06885g⟩. ⟨hal-03799120v2⟩