Tracking asphalt markers in bitumen oil paint reconstructions by Py-TMAH-GC/MS and Py-GCxGC/MS

Raquel Marques (1) , Michel Sablier (2) , Jaap Boon , Gauthier Rosé (2, 3) , Leslie Carlyle (1) , Isabel Pombo Cardoso (1) , Laurence de Viguerie (3)

1 NOVA - Universidade Nova de Lisboa = NOVA University Lisbon
2 CRC - Centre de Recherche sur la Conservation
3 LAMS - Laboratoire d'Archéologie Moléculaire et Structurale

Bitumen brown oil paint reconstructions based on 19th century production records from the British colourman Winsor & Newton were analysed using thermally assisted methylation with tetramethylammonium hydroxide (Py-TMAH-GC/MS), and pyrolysis comprehensive two-dimensional gas chromatography (Py-GCxGC/MS). Reconstructions were compared with the starting material, Trinidad Lake asphalt (TLA), to determine how detectable this asphalt is after heat processing in lead treated linseed oil. The use of brown paint containing asphalt/bitumen (the names are used interchangeably) was blamed for severe film-forming defects in 18th and 19th century oil paintings, yet this material has rarely been identified in earlier studies of historical paintings. This research offers a possible explanation for the paucity of evidence as it reveals that asphalt markers identified in the TLA disappear in the first stage of reconstructing bitumen brown oil paint.

Mots clés: Py-TMAH-GC/MS; Py-GCxGC/MS; Trinidad Lake Asphalt; Bitumen Oil Paint; Alligatoring

Domaines: Chimie analytique; Art et histoire de l'art

Raquel Marques, Michel Sablier, Jaap Boon, Gauthier Rosé, Leslie Carlyle, et al.. Tracking asphalt markers in bitumen oil paint reconstructions by Py-TMAH-GC/MS and Py-GCxGC/MS. Microchemical Journal, 2022, 181, pp.107762. ⟨10.1016/j.microc.2022.107762⟩. ⟨hal-03788587⟩