A mesoporous metal–organic framework used to sustainably release copper( ii ) into reducing aqueous media to promote the CuAAC click reaction

Pascal Hoffmann (1) , Christian Lherbet (1) , Isabelle Fabing (2) , Marie-Claire Barthélémy (3) , Yann Borjon-Piron (3) , Christophe Laurent (3) , Alain Vigroux (1)

1 SPCMIB - Synthèse et Physico-Chimie de Molécules d'Intérêt Biologique
2 ICT - Institut de Chimie de Toulouse
3 CIRIMAT - Centre interuniversitaire de recherche et d'ingenierie des matériaux

Cr-MIL-101-NH 2 (MOF1) has been used to encapsulate large amounts of copper sulfate and the resulting loaded material, Cu@MOF1, was successfully used to promote the CuAAC click reaction.

Domaines: Chimie; Matériaux

Pascal Hoffmann, Christian Lherbet, Isabelle Fabing, Marie-Claire Barthélémy, Yann Borjon-Piron, et al.. A mesoporous metal–organic framework used to sustainably release copper( ii ) into reducing aqueous media to promote the CuAAC click reaction. RSC Advances, 2022, 12 (41), pp.26825-26833. ⟨10.1039/d2ra04298c⟩. ⟨hal-03785805⟩