Synthesis, Reactivity, and Ligand Properties of a Stable Alkyl Carbene

Vincent Lavallo (1) , John Mafhouz (1) , Yves Canac (1) , Bruno Donnadieu (1) , Wolfgand Schoeller (2) , Guy Bertrand (1)

1 UMI 2957 - UCR - CNRS joint research chemistry laboratory
2 Fakultät für Chemie [Universität Bielefeld]

Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments.

Mots clés: Alkyls; Carbene compounds; Hydrocarbons; Ligands; Metals

Domaines: Chimie de coordination

Vincent Lavallo, John Mafhouz, Yves Canac, Bruno Donnadieu, Wolfgand Schoeller, et al.. Synthesis, Reactivity, and Ligand Properties of a Stable Alkyl Carbene. Journal of the American Chemical Society, 2004, 126 (28), pp.8670-8671. ⟨10.1021/ja047503f⟩. ⟨hal-03739732⟩