Reduction of Ammonium Perrhenate by CO: a Convenient Method for Preparing Re2(CO)10

Fausto Calderazzo (1) , Rinaldo Poli (1)

1 University of Pisa - Università di Pisa

Decacarbonyldirhenium(0), Re2(CO)10, was obtained in yields as high as 69% by carbonylation of ammonium perrhenate(VII) at 250-290 °C with CO at about 150 atm pressure in toluene as medium.

Domaines: Chimie de coordination

Fausto Calderazzo, Rinaldo Poli. Reduction of Ammonium Perrhenate by CO: a Convenient Method for Preparing Re2(CO)10. Gazzetta Chimica Italiana, 1985, 115, pp.573-574. ⟨hal-03583836⟩