Synthesis and molecular structure of mixed-valence compounds of rhenium obtained by di-iodine oxidation of rhenium(I) carbonyl complexes; X-ray crystal structure of Re3I6(CO)6

Fausto Calderazzo (1) , Fabio Marchetti (1) , Rinaldo Poli (1) , Dario Vitali (1) , Pier Francesco Zanazzi (2)

1 University of Pisa - Università di Pisa
2 UNIPG - Università degli Studi di Perugia = University of Perugia

Mixed-valence iodide-bridged compounds of rhenium have been obtained by the di-iodine oxidation of rhenium(I) carbonyl complexes; the X-ray crystal and molecular structure of Re3I6(CO)6, a ReI–ReIV complex of S6 symmetry, is presented.

Domaines: Chimie de coordination; Cristallographie

Fausto Calderazzo, Fabio Marchetti, Rinaldo Poli, Dario Vitali, Pier Francesco Zanazzi. Synthesis and molecular structure of mixed-valence compounds of rhenium obtained by di-iodine oxidation of rhenium(I) carbonyl complexes; X-ray crystal structure of Re3I6(CO)6. Journal of the Chemical Society, Chemical Communications, 1981, 17, pp.893-894. ⟨10.1039/C39810000893⟩. ⟨hal-03545655⟩