Thermal reaction of octacarbonyltetraiododimolybdenum with dimethylphenylphosphine, diethylphenylphosphine and pyridine. Formation of metal-metal quadruple bonds vs. disproportionation. X-ray crystal structures of bis(dimethylphenylphosphine)(dimethylphenylphosphine oxide)triiodomolybdenum and diethylphenylphosphonium bis(diethylphenylphosphine)tetraiodomolybdate(1-)

F. Albert Cotton (1) , Rinaldo Poli (1)

1 Texas A&M University [College Station]

Domaines: Chimie de coordination; Cristallographie

F. Albert Cotton, Rinaldo Poli. Thermal reaction of octacarbonyltetraiododimolybdenum with dimethylphenylphosphine, diethylphenylphosphine and pyridine. Formation of metal-metal quadruple bonds vs. disproportionation. X-ray crystal structures of bis(dimethylphenylphosphine)(dimethylphenylphosphine oxide)triiodomolybdenum and diethylphenylphosphonium bis(diethylphenylphosphine)tetraiodomolybdate(1-). Inorganic Chemistry, 1986, 25 (20), pp.3624-3629. ⟨10.1021/ic00240a019⟩. ⟨hal-03545255⟩