Reactions of CpMoCl2L2 (Cp = .eta.5-C5H5; L = PMe3, PMe2Ph) with methyllithium. Preparation and structure of a molybdenum(II) compound containing an ortho-metalated PMe2Ph ligand: CpMo(o-C6H4PMe2)(PMe2Ph)2

Rinaldo Poli (1) , Steven Krueger (1) , Fatima Abugideiri (1) , Brian Haggerty (2) , Arnold Rheingold (2)

1 University of Maryland [College Park]
2 University of Delaware [Newark]

Domaines: Chimie de coordination; Cristallographie

Rinaldo Poli, Steven Krueger, Fatima Abugideiri, Brian Haggerty, Arnold Rheingold. Reactions of CpMoCl2L2 (Cp = .eta.5-C5H5; L = PMe3, PMe2Ph) with methyllithium. Preparation and structure of a molybdenum(II) compound containing an ortho-metalated PMe2Ph ligand: CpMo(o-C6H4PMe2)(PMe2Ph)2. Organometallics, 1991, 10 (9), pp.3041-3046. ⟨10.1021/om00055a015⟩. ⟨hal-03542817⟩