Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

Marc Devillard (1) , Emmanuel Nicolas , Christian Appelt , Jana Backs , Sonia Mallet-Ladeira , Ghenwa Bouhadir , J. Chris Slootweg , Werner Uhl , Didier Bourissou

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée

Upon coordination of Mes 2 PC(CHPh)Al t Bu 2 , bridging P→M–Cl→Al coordination was observed with Rh and Pd fragments, while chloride abstraction occurred with Au. The resulting zwitterionic complexes have been fully characterized and analyzed by DFT calculations.

Domaines: Chimie

Marc Devillard, Emmanuel Nicolas, Christian Appelt, Jana Backs, Sonia Mallet-Ladeira, et al.. Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold. Chemical Communications, 2014, 50 (94), pp.14805-14808. ⟨10.1039/C4CC06992G⟩. ⟨hal-03539248⟩