The question of metal-metal bonding in edge-sharing bioctahedral molybdenum(III) complexes. Variable temperature proton NMR study of Mo2Cl6(PMexEt3-x)4 (x = 0-3) and the mechanism of the face-sharing to edge-sharing transformation

Rinaldo Poli (1) , John Gordon (1)

1 University of Maryland [College Park]

Domaines: Chimie de coordination

Rinaldo Poli, John Gordon. The question of metal-metal bonding in edge-sharing bioctahedral molybdenum(III) complexes. Variable temperature proton NMR study of Mo2Cl6(PMexEt3-x)4 (x = 0-3) and the mechanism of the face-sharing to edge-sharing transformation. Journal of the American Chemical Society, 1992, 114 (17), pp.6723-6734. ⟨10.1021/ja00043a017⟩. ⟨hal-03534692⟩