Stable 16-electron, paramagnetic cyclopentadienylmolybenum(II) complexes

Fatima Abugideiri (1) , D. Webster Keogh (1) , Rinaldo Poli (1)

1 University of Maryland [College Park]

Complexes [C5Me5MoClL2](L = tertiary phosphine) are rare examples of stable cyclopentadienylmolybdenum(II) 16-electron complexes and the first such complexes with a spin triplet ground state.

Domaines: Chimie de coordination

Fatima Abugideiri, D. Webster Keogh, Rinaldo Poli. Stable 16-electron, paramagnetic cyclopentadienylmolybenum(II) complexes. Journal of the Chemical Society, Chemical Communications, 1994, 20, pp.2317-2318. ⟨10.1039/C39940002317⟩. ⟨hal-03532950⟩