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Article Dans Une Revue Polyhedron Année : 1995

Crystal structure of base-free [MoOI4]−

Résumé

Air oxidation of [PPh4]3[Mo3I12] produces [PPh4][MoOI4], a rare example of an iodide-containing molybdenum(V) complex, whose structure has been determined by X-ray crystallography. This structural determination completes the [MoOX4]− (X = Cl, Br, I) series. The structural parameters are compared with those of the other halide analogues and with those of crystallographically characterized base adducts, [MoOI4(L)]− (L = H2O, THF). Also, a comparison between the donor power of O2− vs the pentamethyl-cyclopentadienyl anion for molybdenum(V) is made possible by comparing [MoOI4]− with the non-existent (η-C5Me5)MoI4.
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Dates et versions

hal-03531317 , version 1 (18-01-2022)

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John Gordon, Sundeep Mattamana, Rinaldo Poli, Phillip Fanwick. Crystal structure of base-free [MoOI4]−. Polyhedron, 1995, 14 (10), pp.1339-1342. ⟨10.1016/0277-5387(94)00397-W⟩. ⟨hal-03531317⟩
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