Preparation of hierarchical SSZ-13 by NH4F etching
Résumé
NH4-SSZ-13 was etched with an aqueous solution of 40 w/% NH4F under different time/temperature conditions to obtain hierarchical derivatives. The etched zeolites were characterized by XRD, SEM, N2 physisorption, 29 Si /27 Al /19 F MAS NMR, ICP-AES, and their acidity monitored by in situ FTIR spectroscopy using acetonitrile as a probe molecule. The results highlight that the zeolite is very sensitive to high temperature and high liquid-solid ratio treatments leading to substantial crystallinity losses. These two parameters need careful tuning to obtain hierarchical derivatives retaining important characteristics as micropore volume and framework Si/Al ratio. The catalytic activity of the modified SSZ-13 is evaluated in the n-propanol conversion.
Domaines
Chimie
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