An experimental and modeling study of the oxidation of 3-pentanol at high pressure

Maxime Carbonnier (1, 2) , Zeynep Serinyel (1) , Alan Keromnes (2) , Guillaume Dayma (1) , Benoîte Lefort (2) , Luis Le Moyne (2) , Philippe Dagaut (1)

1 ICARE - Institut de Combustion, Aérothermique, Réactivité et Environnement
2 DRIVE - Département de Recherche en Ingéniérie des Véhicules pour l'Environnement

High pressure oxidation of 3-pentanol is investigated in a jet-stirred reactor and in a shock tube. Experiments in the reactor were carried out at 10 atm, between 730 and 1180 K, for equivalence ratios of 0.35, 0.5, 1, 2, 4 and 1000 ppm fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were recorded using Fourier transform infrared spectroscopy (FTIR) and gas chromatography (GC). Ignition delay times were measured for 3-pentanol/O2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1000–1470 K and for equivalence ratios of 0.5, 1 and 2. The fuel did not show any low-temperature reactivity under these conditions in neither experimental set-up and produced various aldehydes and ketones as well as the olefin 2-pentene as intermediates. A kinetic sub-mechanism is developed in order to represent the present data and analyze the reaction pathways.

Mots clés: Shock tube; Jet-stirred reactor; Kinetics modeling; 3-pentanol; ignition

Domaines: Milieux fluides et réactifs

Maxime Carbonnier, Zeynep Serinyel, Alan Keromnes, Guillaume Dayma, Benoîte Lefort, et al.. An experimental and modeling study of the oxidation of 3-pentanol at high pressure. Proceedings of the Combustion Institute, 2019, 37 (1), pp.477-484. ⟨10.1016/j.proci.2018.07.114⟩. ⟨hal-02011316⟩