Approaching industrially relevant current densities for hydrogen oxidation with a bioinspired molecular catalytic material

Jérémy Schild (1, 2) , Bertrand Reuillard (1) , Adina Morozan (1) , Pascale Chenevier (3) , Edmond Gravel (2) , Eric Doris (2) , Vincent Artero (1)

1 SolHyCat - Solar fuels, hydrogen and catalysis
2 SCBM - Service de Chimie Bio-Organique et de Marquage
3 STEP - Synthèse, Structure et Propriétés de Matériaux Fonctionnels

Integration of efficient platinum-group-metal (PGM)-free catalysts to fuel cells and electrolyzers is a prerequisite to their large-scale deployment. Here, we describe the development of a molecular-based anode for the hydrogen oxidation reaction (HOR) through noncovalent integration of a DuBois type Ni bioinspired molecular catalyst at the surface of a carbon nanotube modified gas diffusion layer. This mild immobilization strategy enabled us to gain high control over the loading in catalytic sites. Additionally, through the adjustment of the hydration level of the active layer, a new record current density of 214 ± 20 mA cm$^{–2}$ could be reached at 0.4 V vs RHE with the PGM-free anode, at 25 °C. Near industrially relevant current densities were obtained at 55 °C with 150 ± 20 and 395 ± 30 mA cm$^{–2}$ at 0.1 and 0.4 V overpotentials, respectively. These results further demonstrate the relevance of such molecular approaches for the development of electrocatalytic platforms for energy conversion.

Domaines: Matériaux; Catalyse

Jérémy Schild, Bertrand Reuillard, Adina Morozan, Pascale Chenevier, Edmond Gravel, et al.. Approaching industrially relevant current densities for hydrogen oxidation with a bioinspired molecular catalytic material. Journal of the American Chemical Society, 2021, 143 (43), pp.18150-18158. ⟨10.1021/jacs.1c07093⟩. ⟨hal-03406054⟩