Evolution of substructure in low-interstitial martensitic stainless steel during tempering

F. Niessen (1) , D. Apel (1) , Frederic Danoix (2) , J. Hald (1) , M.A.J. a J Somers (1)

1 DTU - Danmarks Tekniske Universitet = Technical University of Denmark
2 GPM - Groupe de physique des matériaux

The evolution of the substructure and the distribution of interstitial elements in lath martensite during tempering in soft martensitic stainless steel X4CrNiMo16-5-1 was studied with line profile analysis of diffractograms from energy dispersive synchrotron X-ray diffraction, local chemical analysis with atom probe tomography and orientation mapping with electron backscatter and transmission Kikuchi diffraction. Martensite formation occurred below 135°C without auto-tempering and led to a dislocation density in martensite of 3.8 • 10 15 m −2 , as determined from X-ray line profile analysis. On tempering, carbon and nitrogen segregated to low-angle and high-angle grain boundaries. Recovery commenced above 550°C and led to a reduction in dislocation density to a steady value of 4 • 10 14 m −2 from 600 to 750°C. Further tempering led to a second increase in dislocation density at room temperature, owing to the transformation of reverted austenite, formed above 650°C, into martensite on cooling. It was observed that the recovery of martensite competes with the formation of reverted austenite. The interpretation of the coherently diffracting domain size obtained from X-ray line profile analysis was critically discussed in the context of the internal structure in martensite.

Mots clés: Tempered martensite; Lath martensite; X-ray line profile analysis; Orientation mapping; Micro-segregation; Atom probe tomography

Domaines: Matériaux

F. Niessen, D. Apel, Frederic Danoix, J. Hald, M.A.J. a J Somers. Evolution of substructure in low-interstitial martensitic stainless steel during tempering. Materials Characterization, 2020, 167, pp.110494. ⟨10.1016/j.matchar.2020.110494⟩. ⟨hal-03365756⟩