Synthesis and Structure of the Stable Paramagnetic Cyclopentadienyl Polyhydride Complexes [Cp*MH 3 (dppe)] + (M = Mo, W): Stronger M−H Bonds upon Oxidation

Brett Pleune (1) , Rinaldo Poli (2) , James Fettinger (1)

1 Chemistry and Biochemistry Department (University of Maryland)
2 LSEO - Laboratoire de Synthèse et Electrosynthèse Organométalliques

Mots clés: Ligands; Organic reactions; Electron paramagnetic resonance spectroscopy; Solvents; Oxidation

Domaines: Chimie de coordination

Brett Pleune, Rinaldo Poli, James Fettinger. Synthesis and Structure of the Stable Paramagnetic Cyclopentadienyl Polyhydride Complexes [Cp*MH 3 (dppe)] + (M = Mo, W): Stronger M−H Bonds upon Oxidation. Journal of the American Chemical Society, 1998, 120 (13), pp.3257-3258. ⟨10.1021/ja9729488⟩. ⟨hal-03312612⟩