Reversible P–C bond formation for saturated α-aminophosphine ligands in solution: stabilization by coordination to Cu(I)

Jacques Andrieu (1) , Jochen Dietz (1) , Rinaldo Poli (1) , Philippe Richard (1)

1 LSEO - Laboratoire de Synthèse et Electrosynthèse Organométalliques

The saturated α-aminophosphine ligands containing a secondary amine function Ph2PCH(R′)NHR″ establish a solution equilibrium with Ph2PH and R′CH2NR″ and are stabilized by electron-withdrawing substituents R′ and R″ and by coordination of the phosphorous donor to Cu(I).

Domaines: Chimie de coordination; Chimie théorique et/ou physique

Jacques Andrieu, Jochen Dietz, Rinaldo Poli, Philippe Richard. Reversible P–C bond formation for saturated α-aminophosphine ligands in solution: stabilization by coordination to Cu(I). New Journal of Chemistry, 1999, 23 (6), pp.581-583. ⟨10.1039/A902783A⟩. ⟨hal-03299574⟩