High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

Funda Demirhan (1, 2) , Jenny Gun (3) , Ovadia Lev (3) , Alexandre Modestov (3) , Rinaldo Poli (1) , Philippe Richard (1)

1 LSEO - Laboratoire de Synthèse et Electrosynthèse Organométalliques
2 Department of Chemistry, Faculty of Sciences & Liberal Arts, Celal Bayar University
3 HUJ - The Hebrew University of Jerusalem

Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH–H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF3)3]+ and [Zn2(O2CCF3)6]2− ions after crystallisation from THF–Et2O.

Domaines: Chimie de coordination; Cristallographie

Funda Demirhan, Jenny Gun, Ovadia Lev, Alexandre Modestov, Rinaldo Poli, et al.. High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5. Journal of the Chemical Society Dalton Transactions, 2002, 10, pp.2109-2111. ⟨10.1039/B203583A⟩. ⟨hal-03284323⟩