Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]

Michael Knorr (1) , Lydie Viau (1) , Yoann Rousselin (2) , Marek Kubicki (2)

1 UTINAM - Univers, Transport, Interfaces, Nanostructures, Atmosphère et environnement, Molécules (UMR 6213)
2 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]

The polymeric title compound, [Cu 2 Br 2 (C 4 H 8 S) 2 ] n , CP1 , represents an example of a two-dimensional coordination polymer resulting from reaction of CuBr with tetrahydrothiophene (THT) in MeCN solution. The two-dimensional layers consist of two different types of rhomboid-shaped dinuclear Cu(μ 2 -Br) 2 Cu secondary building units (SBUs); one with a quite loose Cu...Cu separation of 3.3348 (10) Å and a second one with a much closer intermetallic contact of 2.9044 (9) Å. These SBUs are interconnected through bridging THT ligands, in which the S atom acts as a four-electron donor bridging each Cu(μ 2 -Br) 2 Cu unit in a μ 2 -bonding mode. In the crystal, the layers are linked by very weak C—H...·Br hydrogen bonds with H...Br distances of 2.95 Å, thus giving rise to a three-dimensional supramolecular network.

Mots clés: crystal structure; two-dimensional coordination polymer; Cu2Br2 rhomboids; tetra­hydro­thio­phene; C—H...Br hydrogen bonding..

Domaines: Chimie de coordination; Polymères; Cristallographie

Michael Knorr, Lydie Viau, Yoann Rousselin, Marek Kubicki. Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]. Acta crystallographica Section E : Crystallographic communications [2015-..], 2021, 77 (7), pp.744-748. ⟨10.1107/S2056989021006460⟩. ⟨hal-03271059⟩