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Dual Electroactivity in a Covalent Organic Network with Mechanically Interlocked Pillar[5]arenes

Abstract : The synthesis and characterization of a polyrotaxanated covalent organic network (CON) based on the association between the viologen and pillar[5]arene (P[5]OH) units are reported. The mechanical bond allows for the irreversible insertion of n-type redox centers (P[5]OH macrocycles) within a pristine structure based on p-type viologen redox centers. Both redox units are active on a narrow potential range and, in water, the presence of P[5]OH greatly increases the electroactivity of the material.
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https://hal.archives-ouvertes.fr/hal-03258960
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Submitted on : Friday, July 2, 2021 - 4:33:09 PM
Last modification on : Tuesday, December 7, 2021 - 2:44:06 PM
Long-term archiving on: : Sunday, October 3, 2021 - 8:21:25 PM

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Benoit Colasson, Thomas Devic, Joël Gaubicher, Charlotte Martineau‐corcos, Philippe Poizot, et al.. Dual Electroactivity in a Covalent Organic Network with Mechanically Interlocked Pillar[5]arenes. Chemistry - A European Journal, Wiley-VCH Verlag, In press, ⟨10.1002/chem.202100558⟩. ⟨hal-03258960⟩

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