Enantioselective Indium-Catalyzed Transformations

Hélène Pellissier (1)

1 ISM2 - Institut des Sciences Moléculaires de Marseille

This review updates the field of enantioselective indiumcatalyzed transformations of all types since 2012. It shows that asymmetric indium catalysis, that suits the growing demand for greener processes, offers a real opportunity to replace toxic metals in the near future. 1 Introduction 2 Allylations, Propargylations, and Allenylations of Carbonyl Compounds and Derivatives 2.1 Allylations 2.2 Propargylations and Allenylations 3 Cycloadditions 3.1 Hetero-Diels-Alder Cycloadditions 3.2 1,3-Dipolar Cycloadditions 4 Miscellaneous Reactions 5 Domino and Tandem Reactions 6 Conclusion

Mots clés: asymmetric indium catalysis; enantioselective reactions; metal catalysis; chirality; asymmetric catalysis

Domaines: Chimie organique; Catalyse

Hélène Pellissier. Enantioselective Indium-Catalyzed Transformations. Synthesis: Journal of Synthetic Organic Chemistry, 2021, 53 (8), pp.1379 - 1395. ⟨10.1055/a-1348-9122⟩. ⟨hal-03205972⟩