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Article Dans Une Revue Chemical Communications Année : 2021

A near-infrared emitting MOF: controlled encapsulation of a fluorescein sensitizer at the time of crystal growth

Résumé

We report here a near-infrared (NIR) emitting lanthanide-based metal-organic framework (MOF) in which Yb 3+ cations are sensitized by fluorescein (FL) as a low energy absorbing chromophore (FL@CD-MOF-161). The unique design of CD-MOF-161 allows for the entrapment of FL molecules in its pores during the synthesis and crystal growth, ensuring the efficient loading and spreading of chromophores within the crystal volume.
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Dates et versions

hal-03192826 , version 1 (08-04-2021)

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Guillaume Collet, Antonio Hrvat, Svetlana Eliseeva, Céline Besnard, Anton Kovalenko, et al.. A near-infrared emitting MOF: controlled encapsulation of a fluorescein sensitizer at the time of crystal growth. Chemical Communications, 2021, 57 (27), pp.3351-3354. ⟨10.1039/d0cc08234a⟩. ⟨hal-03192826⟩
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