Controlled Reactivity of Phosphonates by Temporary Silicon Connection

Bogdan Iorga (1) , Philippe Savignac (1)

1 DCPH - Laboratoire Hétéroéléments et Coordination

In this review a summary of the different syntheses of trimethylsilylphosphonates is given. Their chemical reactivity in the light of their synthetic utility leading to numerous types of functionalized phosphonates is described. The material is presented according to the role played by the trimethylsilyl group.

Mots clés: phosphonate carbanion; Peterson reaction; silicon; halogenation; alkylations

Domaines: Chimie organique

Bogdan Iorga, Philippe Savignac. Controlled Reactivity of Phosphonates by Temporary Silicon Connection. SYNLETT, 2001, 2001 (4), pp.447-457. ⟨10.1055/s-2001-12309⟩. ⟨hal-03161508⟩