Ruthenium and Osmium Metalloradicals

Rinaldo Poli (1, 2)

1 LCC - Laboratoire de chimie de coordination
2 IUF - Institut universitaire de France

Radical design: Unprecedented stability of ruthenium(I) and osmium(I) complexes with metalloradical character has been achieved by use of judiciously chosen supporting ligands based on the tris(o‐phosphinophenyl)silyl motif. The pronounced radical character on the ruthenium(I) center is also enforced by non‐innocent ligands of the diiminopyridine type.

Mots clés: Dinitrogen; Non‐innocent ligands; Osmium; Radicals; Ruthenium; Dinitrogen

Domaines: Chimie de coordination

Rinaldo Poli. Ruthenium and Osmium Metalloradicals. Angewandte Chemie International Edition, 2011, 50 (1), pp.43-45. ⟨10.1002/anie.201002715⟩. ⟨hal-03158361⟩