Straightforward coordination-driven supramolecular chemistry preparation of a discrete solid-state luminescent Cu4 polymetallic compact assembly based on conformationally flexible building blocks - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Inorganica Chimica Acta Année : 2021

Straightforward coordination-driven supramolecular chemistry preparation of a discrete solid-state luminescent Cu4 polymetallic compact assembly based on conformationally flexible building blocks

Résumé

The ditopic nitrile-capped 1,4-phenylenediacetonitrile linker L3 featuring partial conformational flexibility was reacted with a flexible pre-assembled Cu(I) dimer stabilized by the bis(diphenyl-phosphino)methane dppm ligand along adaptive coordination-driven supramolecular assembling processes. It resulted in the selective and unexpected formation of a compact tetrametallic assembly associating two bimetallic building blocks with three ditopic linkers. The solid-state photophysical studies of this original Cu(I)-based assembly were analysed and showed its attractive luminescence properties.
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hal-03130407 , version 1 (18-02-2021)

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Sloane Evariste, Chendong Xu, Guillaume Calvez, Christophe Lescop. Straightforward coordination-driven supramolecular chemistry preparation of a discrete solid-state luminescent Cu4 polymetallic compact assembly based on conformationally flexible building blocks. Inorganica Chimica Acta, 2021, 516, pp.120115. ⟨10.1016/j.ica.2020.120115⟩. ⟨hal-03130407⟩
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