Total Synthesis of (−)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane

Romain Coffinier , Mourad El Assal , Philippe Peixoto (1, 2) , Cyril Bosset , Karinne Miqueu , Jean-Marc Sotiropoulos , Laurent Pouységu , Stéphane Quideau

1 UB - Université de Bordeaux
2 CNRS - Centre National de la Recherche Scientifique

Domaines: Chimie; Sciences du Vivant [q-bio]

Romain Coffinier, Mourad El Assal, Philippe Peixoto, Cyril Bosset, Karinne Miqueu, et al.. Total Synthesis of (−)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane. Organic Letters, 2016, 18 (5), pp.1120-1123. ⟨10.1021/acs.orglett.6b00224⟩. ⟨hal-03034070⟩